Synthesis of 1, 2, 4-triazoles and thiazoles from thiosemicarbazide and its derivatives

SM Mustafa, VA Nair, JP Chittoor… - Mini-Reviews in …, 2004 - ingentaconnect.com
The use of thiosemicarbazide in organic synthesis has become a classical strategy for the
synthesis of several heterocycles. Their reactions with compounds containing C= O and C …

Chemistry and heterocyclization of thiosemicarbazones

AA Hassan, AM Shawky… - Journal of Heterocyclic …, 2012 - Wiley Online Library
Chemistry and heterocyclization of thiosemicarbazones - Hassan - 2012 - Journal of
Heterocyclic Chemistry - Wiley Online Library Skip to Article Content Skip to Article Information …

Efficient syntheses of thiadiazoline and thiadiazole derivatives by the cyclization of 3-aryl-4-formylsydnone thiosemicarbazones with acetic anhydride and ferric …

MH Shih, CL Wu - Tetrahedron, 2005 - Elsevier
3-Aryl-4-formylsydnone 4′-phenylthiosemicarbazones and 3-aryl-4-formylsydnone
thiosemicarbazones are effective precursors of sydnonyl-substituted heterocycles. The …

Regioselectivity in 1, 5-electrocyclization of N-[as-triazin-3-yl] nitrilimines. Synthesis of s-triazolo [4, 3-b]-as-triazin-7 (8H)-ones

AS Shawali, SM Gomha - Tetrahedron, 2002 - Elsevier
6-Benzyl-3-(arylmethylidenehydrazino)-as-triazin-5 (4H)-ones 4 underwent regioselective
cyclization upon treatment with either bromine in acetic acid containing sodium acetate or …

Synthesis and Antibacterial Activity of 4‐Aryl‐2‐(1‐substituted ethylidene) thiazoles

AA Hassan, YR Ibrahim, EM El‐Sheref… - Archiv der …, 2013 - Wiley Online Library
(E)‐4‐Aryl‐2‐[2‐(1‐substituted ethylidene) hydrazinyl] thiazoles and (Z)‐3‐substituted‐4‐
aryl‐2‐[(E)‐(1‐phenylethylidene) hydrazono]‐2, 3‐dihydrothiazoles were synthesized by the …

A quantitative study of substituent effects on oxidative cyclization of some 2‐aryl‐substituted aldehyde thiosemicarbazones induced by ferric chloride and cupric …

R Noto, PL Meo, M Gruttadauria… - Journal of heterocyclic …, 1999 - Wiley Online Library
As a development of our previous work, we performed a kinetic study of the oxidative
cyclization reaction of some 2, 4‐diaryl‐substituted aldehyde thiosemicarbazones 1a‐n …

Metal‐Catalysed Oxidation Processes in Thiosemicarbazones: New Complexes with the Ligand N‐{2‐([4‐N‐Ethylthiosemicarbazone]methyl)phenyl}‐p …

R Pedrido, MJ Romero, MR Bermejo… - … A European Journal, 2008 - Wiley Online Library
The coordination behaviour of a new thiosemicarbazone Schiff‐base building block, N‐{2‐
([4‐N‐ethylthiosemicarbazone] methyl) phenyl}‐p‐toluenesulfonamide, H2L1 (1) …

Eine neue Synthese von Heterocyclen aus Thiocarbohydraziden

AA Hassan, NK Mohamed, AA Aly… - Monatshefte für Chemie …, 1997 - Springer
The reaction of thiocarbohydrazides 1a and thiocarbazones 1b with tetracyanoethylene
(TCNE) afforded the thiazol, thiadiazole, thiazine, and thiadiazepine derivatives 4–7. 2 …

Mechanisms of the cascade synthesis of substituted 4‐amino‐1, 2, 4‐triazol‐3‐one from huisgen zwitterion and aldehyde hydrazone: A DFT study

W Zhang, Y Zhu, D Wei, M Tang - Journal of Computational …, 2012 - Wiley Online Library
The detailed reaction mechanisms of the title reaction are shed light on by using the density
functional theory (DFT). The calculated results have demonstrated that the whole reaction …

Photocyclization reaction of some 2-methyl-4-phenyl-substituted aldehyde thiosemicarbazones. Mechanistic aspects

S Buscemi, M Gruttadauria - Tetrahedron, 2000 - Elsevier
Irradiation of 2-methyl-4-phenyl-substituted benzaldehyde thiosemicarbazones led with
good yields to the corresponding Δ2-1, 2, 4-triazoline-5-thione derivatives through the …