Carboxylate-assisted transition-metal-catalyzed C− H bond functionalizations: mechanism and scope

L Ackermann - Chemical reviews, 2011 - ACS Publications
The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Iron-catalyzed C–H bond activation

R Shang, L Ilies, E Nakamura - Chemical Reviews, 2017 - ACS Publications
Catalytic C–H bond activation, which was an elusive subject of chemical research until the
1990s, has now become a standard synthetic method for the formation of new C–C and C …

Oxidative coupling between two hydrocarbons: an update of recent C–H functionalizations

C Liu, J Yuan, M Gao, S Tang, W Li, R Shi… - Chemical …, 2015 - ACS Publications
C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis

SH Newman-Stonebraker, SR Smith, JE Borowski… - Science, 2021 - science.org
Chemists often use statistical analysis of reaction data with molecular descriptors to identify
structure-reactivity relationships, which can enable prediction and mechanistic …

Key Green Chemistry research areas from a pharmaceutical manufacturers' perspective revisited

MC Bryan, PJ Dunn, D Entwistle, F Gallou… - Green …, 2018 - pubs.rsc.org
In 2007 the members of the ACS Green Chemistry Institute® Pharmaceutical Roundtable
assembled a list of key green chemistry research areas to both identify transformations that …

Transition-metal-free coupling reactions

CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Organocatalysis in inert C–H bond functionalization

Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Synthetic molecular photoelectrochemistry: new frontiers in synthetic applications, mechanistic insights and scalability

S Wu, J Kaur, TA Karl, X Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

C Shen, P Zhang, Q Sun, S Bai, TSA Hor… - Chemical Society …, 2015 - pubs.rsc.org
The development of mild and general methods for C–S bond formation has received
significant attention because the C–S bond is indispensable in many important biological …

C–H functionalization of azines

K Murakami, S Yamada, T Kaneda, K Itami - Chemical Reviews, 2017 - ACS Publications
Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …