Magnetic cluster excitations
A Furrer, O Waldmann - Reviews of Modern Physics, 2013 - APS
Magnetic clusters, ie, assemblies of a finite number (between two or three and several
hundred) of interacting spin centers which are magnetically decoupled from their …
hundred) of interacting spin centers which are magnetically decoupled from their …
Beyond the spin model: exchange coupling in molecular magnets with unquenched orbital angular momenta
In this critical review we review the problem of exchange interactions in polynuclear metal
complexes involving orbitally degenerate metal ions. The key feature of these systems is …
complexes involving orbitally degenerate metal ions. The key feature of these systems is …
Toward molecular 4f single-ion magnet qubits
Quantum coherence is detected in the 4f single-ion magnet (SIM) Yb (trensal), by isotope
selective pulsed EPR spectroscopy on an oriented single crystal. At X-band, the spin–lattice …
selective pulsed EPR spectroscopy on an oriented single crystal. At X-band, the spin–lattice …
Molecular nanomagnets for information technologies
M Affronte - Journal of Materials Chemistry, 2009 - pubs.rsc.org
Nanomagnets will play a crucial role for the storage and processing of magnetic information
in the future, so we may wonder to what extent molecular systems will contribute to this …
in the future, so we may wonder to what extent molecular systems will contribute to this …
Direct observation of quantum coherence in single-molecule magnets
C Schlegel, J Van Slageren, M Manoli, EK Brechin… - Physical review …, 2008 - APS
Direct evidence of quantum coherence in a single-molecule magnet in a frozen solution is
reported with coherence times as long as T 2= 630±30 ns. We can strongly increase the …
reported with coherence times as long as T 2= 630±30 ns. We can strongly increase the …
Density functional studies on dinuclear {Ni II Gd III} and trinuclear {Ni II Gd III Ni II} complexes: magnetic exchange and magneto-structural maps
Theoretical calculations using density functional methods have been performed on two
dinuclear {NiII–GdIII} and two trinuclear {NiII–GdIII–NiII} complexes having two and three μ …
dinuclear {NiII–GdIII} and two trinuclear {NiII–GdIII–NiII} complexes having two and three μ …
Studying Cation Exchange in {Cr7Co} Pseudorotaxanes: Preparatory Studies for Making Hybrid Molecular Machines
In the design of dynamic supramolecular systems used in molecular machines, it is
important to understand the binding preferences between the macrocycle and stations along …
important to understand the binding preferences between the macrocycle and stations along …
Ringing the changes in Fe III/Yb III cyclic coordination clusters
A Baniodeh, CE Anson, AK Powell - Chemical Science, 2013 - pubs.rsc.org
Five [FeIIImYbIIIn] Cyclic Coordination Clusters (CCCs) which show completely different
arrangements of their cyclic cores have been synthesised and characterised. These …
arrangements of their cyclic cores have been synthesised and characterised. These …
Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements
AA Starikova, VI Minkin - Russian Chemical Reviews, 2018 - iopscience.iop.org
The currently available literature data on the synthesis, molecular and electronic structure of
mixed-ligand complexes (adducts) of transition metals (chromium, manganese, iron, cobalt …
mixed-ligand complexes (adducts) of transition metals (chromium, manganese, iron, cobalt …
Spectroscopic Investigation of a Metal–Metal-Bonded Fe6 Single-Molecule Magnet with an Isolated S = 19/2 Giant-Spin Ground State
J Nehrkorn, SM Greer, BJ Malbrecht… - Inorganic …, 2021 - ACS Publications
The metal–metal-bonded molecule [Bu4N][(HL) 2Fe6 (dmf) 2](Fe6) was previously shown to
possess a thermally isolated spin S= 19/2 ground state and found to exhibit slow …
possess a thermally isolated spin S= 19/2 ground state and found to exhibit slow …