Mechanistic and Kinetic Insights into Cellular Uptake of Biomimetic Dinitrosyl Iron Complexes and Intracellular Delivery of NO for Activation of Cytoprotective HO-1

H Chiu, A Chau Fang, YH Chen, RX Koi, KC Yu… - JACS Au, 2024 - ACS Publications
Dinitrosyl iron unit (DNIU),[Fe (NO) 2], is a natural metallocofactor for biological storage,
delivery, and metabolism of nitric oxide (NO). In the attempt to gain a biomimetic insight into …

Ligand Control of Dinitrosyl Iron Complexes for Selective Superoxide-Mediated Nitric Oxide Monooxygenation and Superoxide–Dioxygen Interconversion

CJ Liao, YT Tseng, YA Cheng, LA Dayao… - Journal of the …, 2023 - ACS Publications
Through nitrosylation of [Fe–S] proteins, or the chelatable iron pool, a dinitrosyl iron unit
(DNIU)[Fe (NO) 2] embedded in the form of low-molecular-weight/protein-bound dinitrosyl …

Principal Role of EPR Method in Discovery, Identification and Study of Dinitrosyl Iron Complexes in Living Organisms

AF Vanin - Applied Magnetic Resonance, 2024 - Springer
This review is directly related to the new field of biology and medicine—the biology and
medicine of nitric oxide (NO)—the simplest molecule produced in all living organisms and …

Electronic Structure and Transformation of Dinitrosyl Iron Complexes (DNICs) Regulated by Redox Non-Innocent Imino-Substituted Phenoxide Ligand

WY Wu, WY Zheng, WT Chen, FT Tsai… - Inorganic …, 2024 - ACS Publications
The coupled NO-vibrational peaks [IR νNO 1775 s, 1716 vs, 1668 vs cm–1 (THF)] between
two adjacent [Fe (NO) 2] groups implicate the electron delocalization nature of the singly O …

The influence of exogenous and endogenous nitric oxide on the human and animal body

AF Vanin - PULMONOLOGIYA, 2024 - journal.pulmonology.ru
It has been shown that the inhalation of gaseous NO (exogenous nitric oxide) leads to the
formation of nitrosonium cations (NO+) in the circulating blood of humans and animals …

Влияние экзогенного и эндогенного оксида азота на организм человека и животных

АФ Ванин - Пульмонология, 2024 - journal.pulmonology.ru
Аннотация Показано, что ингаляция газообразного NO (экзогенного оксида азота) в
ходе окисления NO приводит к появлению в циркулирующей крови человека и …

Mechanisms of the Formation and Function of Dinitrosyl Iron Complexes as a “Working Form” of Nitric Oxide in Living Organisms

AF Vanin - Biofizika, 2024 - journals.rcsi.science
It has been proposed that only the introduction of endogenous nitric oxide (NO) into
dinitrosyl iron complexes (DNIC) or S-nitrosothiols (RS-NO) can ensure stabilization of NO …