Free energies of proton-coupled electron transfer reagents and their applications

RG Agarwal, SC Coste, BD Groff, AM Heuer… - Chemical …, 2021 - ACS Publications
We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Absolute band-edge energies are over-emphasized in the design of photoelectrochemical materials

AJ Kaufman, AC Nielander, GJ Meyer, S Maldonado… - Nature Catalysis, 2024 - nature.com
The absolute band-edge potentials of semiconductors and their positions relative to solution
redox potentials are often invoked as design principles for photoelectrochemical devices …

Bonds over electrons: proton coupled electron transfer at solid–solution interfaces

JM Mayer - Journal of the American Chemical Society, 2023 - ACS Publications
This Perspective argues that most redox reactions of materials at an interface with a protic
solution involve net proton-coupled electron transfer (PCET)(or other cation-coupled ET) …

Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells

MK Brennaman, RJ Dillon, L Alibabaei… - Journal of the …, 2016 - ACS Publications
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …

A surface science perspective on TiO2 photocatalysis

MA Henderson - Surface Science Reports, 2011 - Elsevier
The field of surface science provides a unique approach to understanding bulk, surface and
interfacial phenomena occurring during TiO 2 photocatalysis. This review highlights, from a …

TiO2 photocatalysis and related surface phenomena

A Fujishima, X Zhang, DA Tryk - Surface science reports, 2008 - Elsevier
The field of photocatalysis can be traced back more than 80 years to early observations of
the chalking of titania-based paints and to studies of the darkening of metal oxides in contact …

Proton-coupled electron transfer

DR Weinberg, CJ Gagliardi, JF Hull, CF Murphy… - Chemical …, 2012 - ACS Publications
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …

Theoretical insights into photoinduced charge transfer and catalysis at oxide interfaces

AV Akimov, AJ Neukirch, OV Prezhdo - Chemical reviews, 2013 - ACS Publications
As the world's population increases and substantial industrial growth continues, the energy
demands of society increase rapidly. Although the earth's oil, natural gas, and coal deposits …

Electron transfer dynamics in dye-sensitized solar cells

A Listorti, B O'regan, JR Durrant - Chemistry of Materials, 2011 - ACS Publications
In this review, we address the materials design parameters that control the processes of
charge separation, and thereby device efficiency, in dye-sensitized photoelectrochemical …

Proton-coupled electron transfer

MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …