3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Half-sandwich rare-earth-catalyzed olefin polymerization, carbometalation, and hydroarylation

M Nishiura, F Guo, Z Hou - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus The search for new catalysts for more efficient, selective chemical
transformations and for the synthesis of new functional materials has been a long-standing …

[BOOK][B] The organometallic chemistry of the transition metals

RH Crabtree - 2009 - books.google.com
" One impressive and compressive book.... This review would have to be book size to do full
justice to all the insights in this volume."—Journal of Metals Online Fully updated and …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

M Nishiura, Z Hou - Nature Chemistry, 2010 - nature.com
This Review gives an overview on recent progress in the synthesis and chemistry of rare-
earth metal dialkyl complexes bearing monoanionic ancillary ligands, with an emphasis on …

Selective Cleavage of the Strong or Weak C–C Bonds in Biphenylene Enabled by Rare-Earth Metals

M Zhu, Z Chai, ZJ Lv, T Li, W Liu, J Wei… - Journal of the …, 2023 - ACS Publications
Selective cleavage of C–C bonds within arene rings is of great interest but remains elusive,
especially for the molecules possessing the active and inert C–C bonds. Here, we report that …

C H Bond Activation by f‐Block Complexes

PL Arnold, MW McMullon, J Rieb… - Angewandte Chemie …, 2015 - Wiley Online Library
Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

F-block N-heterocyclic carbene complexes

PL Arnold, IJ Casely - Chemical reviews, 2009 - ACS Publications
The use of N-heterocyclic carbenes as ligands is a rapidly expanding field, and exciting
compounds and catalytic uses are being described for their metal complexes with increasing …

Renaissance of homogeneous cerium catalysts with unique Ce (IV/III) couple: redox-mediated organic transformations involving homolysis of Ce (IV)–ligand covalent …

H Tsurugi, K Mashima - Journal of the American Chemical Society, 2021 - ACS Publications
Recent advances in the catalytic application of cerium complexes were achieved through
controlling the Ce (IV/III) redox couple. Although Ce (IV) complexes have been extensively …

Recent advances in radiometals for combined imaging and therapy in cancer

N Herrero Álvarez, D Bauer, J Hernández‐Gil… - …, 2021 - Wiley Online Library
Nuclear medicine is defined as the use of radionuclides for diagnostic and therapeutic
applications. The imaging modalities positron emission tomography (PET) and single …