Catalytic upgrading of biomass model compounds: novel approaches and lessons learnt from traditional hydrodeoxygenation–a review
W **, L Pastor‐Pérez, DK Shen… - …, 2019 - Wiley Online Library
Catalytic hydrodeoxygenation (HDO) is a fundamental process for bio‐resources upgrading
to produce transportation fuels or added value chemicals. The bottleneck of this technology …
to produce transportation fuels or added value chemicals. The bottleneck of this technology …
Recent advances in the selective catalytic hydrodeoxygenation of lignin-derived oxygenates to arenes
The utilization of lignin-derived compounds is an important part of biomass valorization. One
promising way to achieve this goal is to reduce/eliminate the oxygen content via …
promising way to achieve this goal is to reduce/eliminate the oxygen content via …
Mechanistic classification and benchmarking of polyolefin depolymerization over silica-alumina-based catalysts
Carbon-carbon bond cleavage mechanisms play a key role in the selective deconstruction
of alkanes and polyolefins. Here, we show that the product distribution, which encompasses …
of alkanes and polyolefins. Here, we show that the product distribution, which encompasses …
Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds
Considerable worldwide interest exists in discovering renewable energy sources that can
substitute for fossil fuels. Lignocellulosic biomass, the most abundant and inexpensive …
substitute for fossil fuels. Lignocellulosic biomass, the most abundant and inexpensive …
Hydrogenation and hydrodeoxygenation of aromatic lignin monomers over Cu/C, Ni/C, Pd/C, Pt/C, Rh/C and Ru/C catalysts: Mechanisms, reaction micro-kinetic …
In this integrated in silico and experimental study, the activity, selectivity and mechanisms of
commercially-available noble and transition metal heterogeneous catalysts, on neutral …
commercially-available noble and transition metal heterogeneous catalysts, on neutral …
Hydrodeoxygenation of phenol over Pd catalysts. Effect of support on reaction mechanism and catalyst deactivation
PM de Souza, RC Rabelo-Neto, LEP Borges… - ACS …, 2017 - ACS Publications
This work investigates the effect of the type of support (SiO2, Al2O3, TiO2, ZrO2, CeO2, and
CeZrO2) on the performance of Pd-based catalysts for the hydrodeoxygenation of phenol at …
CeZrO2) on the performance of Pd-based catalysts for the hydrodeoxygenation of phenol at …
Role of keto intermediates in the hydrodeoxygenation of phenol over Pd on oxophilic supports
PM de Souza, RC Rabelo-Neto, LEP Borges… - Acs …, 2015 - ACS Publications
The performance of Pd catalysts supported on SiO2, Al2O3 and ZrO2 for the
hydrodeoxygenation (HDO) of phenol has been compared in the gas phase, at 300° C and 1 …
hydrodeoxygenation (HDO) of phenol has been compared in the gas phase, at 300° C and 1 …
Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta …
Bifunctional metal/acid catalysts of 5 wt% Ni/HBeta, 5 wt% Fe/HBeta, 2.5 wt% Ni-2.5 wt%
Fe/HBeta (NiFe-5/HBeta) and 5 wt% Ni-5 wt% Fe/HBeta (NiFe-10/HBeta) were used for …
Fe/HBeta (NiFe-5/HBeta) and 5 wt% Ni-5 wt% Fe/HBeta (NiFe-10/HBeta) were used for …
Mechanistic Study of the Direct Hydrodeoxygenation of m-Cresol over WOx-Decorated Pt/C Catalysts
Hydrodeoxygenation (HDO) of m-cresol to produce toluene over carbon-supported Pt and Pt-
WO x catalysts was studied. In stark contrast to Pt/C that exhibits only modest selectivity and …
WO x catalysts was studied. In stark contrast to Pt/C that exhibits only modest selectivity and …
Role of the Support and Reaction Conditions on the Vapor-Phase Deoxygenation of m-Cresol over Pt/C and Pt/TiO2 Catalysts
The catalytic deoxygenation of biomass fast pyrolysis vapors offers a promising route for the
sustainable production of liquid transportation fuels. However, a clear understanding of the …
sustainable production of liquid transportation fuels. However, a clear understanding of the …