Catalytic upgrading of biomass model compounds: novel approaches and lessons learnt from traditional hydrodeoxygenation–a review

W **, L Pastor‐Pérez, DK Shen… - …, 2019 - Wiley Online Library
Catalytic hydrodeoxygenation (HDO) is a fundamental process for bio‐resources upgrading
to produce transportation fuels or added value chemicals. The bottleneck of this technology …

Recent advances in the selective catalytic hydrodeoxygenation of lignin-derived oxygenates to arenes

J Zhang, J Sun, Y Wang - Green Chemistry, 2020 - pubs.rsc.org
The utilization of lignin-derived compounds is an important part of biomass valorization. One
promising way to achieve this goal is to reduce/eliminate the oxygen content via …

Mechanistic classification and benchmarking of polyolefin depolymerization over silica-alumina-based catalysts

WT Lee, A van Muyden, FD Bobbink, MD Mensi… - Nature …, 2022 - nature.com
Carbon-carbon bond cleavage mechanisms play a key role in the selective deconstruction
of alkanes and polyolefins. Here, we show that the product distribution, which encompasses …

Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

H Wang, J Male, Y Wang - Acs Catalysis, 2013 - ACS Publications
Considerable worldwide interest exists in discovering renewable energy sources that can
substitute for fossil fuels. Lignocellulosic biomass, the most abundant and inexpensive …

Hydrogenation and hydrodeoxygenation of aromatic lignin monomers over Cu/C, Ni/C, Pd/C, Pt/C, Rh/C and Ru/C catalysts: Mechanisms, reaction micro-kinetic …

A Bjelić, M Grilc, M Huš, B Likozar - Chemical Engineering Journal, 2019 - Elsevier
In this integrated in silico and experimental study, the activity, selectivity and mechanisms of
commercially-available noble and transition metal heterogeneous catalysts, on neutral …

Hydrodeoxygenation of phenol over Pd catalysts. Effect of support on reaction mechanism and catalyst deactivation

PM de Souza, RC Rabelo-Neto, LEP Borges… - ACS …, 2017 - ACS Publications
This work investigates the effect of the type of support (SiO2, Al2O3, TiO2, ZrO2, CeO2, and
CeZrO2) on the performance of Pd-based catalysts for the hydrodeoxygenation of phenol at …

Role of keto intermediates in the hydrodeoxygenation of phenol over Pd on oxophilic supports

PM de Souza, RC Rabelo-Neto, LEP Borges… - Acs …, 2015 - ACS Publications
The performance of Pd catalysts supported on SiO2, Al2O3 and ZrO2 for the
hydrodeoxygenation (HDO) of phenol has been compared in the gas phase, at 300° C and 1 …

Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta …

H Shafaghat, PS Rezaei, WMAW Daud - Journal of industrial and …, 2016 - Elsevier
Bifunctional metal/acid catalysts of 5 wt% Ni/HBeta, 5 wt% Fe/HBeta, 2.5 wt% Ni-2.5 wt%
Fe/HBeta (NiFe-5/HBeta) and 5 wt% Ni-5 wt% Fe/HBeta (NiFe-10/HBeta) were used for …

Mechanistic Study of the Direct Hydrodeoxygenation of m-Cresol over WOx-Decorated Pt/C Catalysts

C Wang, AV Mironenko, A Raizada, T Chen… - ACS …, 2018 - ACS Publications
Hydrodeoxygenation (HDO) of m-cresol to produce toluene over carbon-supported Pt and Pt-
WO x catalysts was studied. In stark contrast to Pt/C that exhibits only modest selectivity and …

Role of the Support and Reaction Conditions on the Vapor-Phase Deoxygenation of m-Cresol over Pt/C and Pt/TiO2 Catalysts

MB Griffin, GA Ferguson, DA Ruddy, MJ Biddy… - ACS …, 2016 - ACS Publications
The catalytic deoxygenation of biomass fast pyrolysis vapors offers a promising route for the
sustainable production of liquid transportation fuels. However, a clear understanding of the …