Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics

BJ Ackley, KL Martin, TS Key, CM Clarkson… - Chemical …, 2023 - ACS Publications
Preceramic polymers (PCPs) are a group of specialty macromolecules that serve as
precursors for generating inorganics, including ceramic carbides, nitrides, and borides …

Polymeric and ceramic silicon-based coatings–a review

G Barroso, Q Li, RK Bordia, G Motz - Journal of materials chemistry A, 2019 - pubs.rsc.org
Silicon-based polymers are outstanding materials for coating applications. These
compounds have excellent properties, such as strong adhesion to most substrates, and high …

Nanoscale control by chemically vapour-deposited polymers

KK Gleason - Nature Reviews Physics, 2020 - nature.com
Chemical vapour deposition (CVD) enables nanoscale control for the synthesis of high-
purity polymer thin films. Ultrathin (< 20 nm) and ultrasmooth (< 1 nm rms roughness) layers …

CVD polymers for devices and device fabrication

M Wang, X Wang, P Moni, A Liu, DH Kim… - Advanced …, 2017 - Wiley Online Library
Chemical vapor deposition (CVD) polymerization directly synthesizes organic thin films on a
substrate from vapor phase reactants. Dielectric, semiconducting, electrically conducting …

Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability

BH Shen, S Wang, WE Tenhaeff - Science advances, 2019 - science.org
Electrochemical reduction of lithium ion battery electrolyte on Si anodes was mitigated by
synthesizing nanoscale, conformal polymer films as artificial solid electrolyte interface (SEI) …

Temperature-mediated structural evolution of vapor–phase deposited cyclosiloxane polymer thin films for enhanced mechanical properties and thermal conductivity

W Du, J Tu, M Qiu, S Zhou, Y Luo… - International Journal of …, 2023 - iopscience.iop.org
Polymer-derived ceramic (PDC) thin films are promising wear-resistant coatings for
protecting metals and carbon–carbon composites from corrosion and oxidation. However …

Imidazole-based artificial synapses for neuromorphic computing: a cluster-type conductive filament via controllable nanocluster nucleation

J Oh, SY Yang, S Kim, C Lee, JH Cha, BC Jang… - Materials …, 2023 - pubs.rsc.org
Memristive synapses based on conductive bridging RAMs (CBRAMs) utilize a switching
layer having low binding energy with active metals for excellent analog conductance …

[HTML][HTML] Vapor deposition routes to conformal polymer thin films

P Moni, A Al-Obeidi, KK Gleason - Beilstein journal of …, 2017 - beilstein-journals.org
Vapor phase syntheses, including parylene chemical vapor deposition (CVD) and initiated
CVD, enable the deposition of conformal polymer thin films to benefit a diverse array of …

Hydrophobization of Inorganic Oxide Surfaces via Ring-Opening Polymerization of Cyclic Siloxane Vapor

KMR Scher, JW Krumpfer - Langmuir, 2023 - ACS Publications
The ability to control the surface chemistry of inorganic oxides has a profound impact on
numerous applications, including lubrication, antifouling, and anticorrosion. While often …

Cyclic polysiloxanes with linked cyclotetrasiloxane subunits

J Yu, Y Liu - Angewandte Chemie International Edition, 2017 - Wiley Online Library
Cyclic polymers are an important class of macromolecules, but the structural diversity of the
backbone is limited. Herein we report the use of the Piers–Rubinsztajn reaction for the one …