Production of hydrogen peroxide by photocatalytic processes

H Hou, X Zeng, X Zhang - Angewandte Chemie International …, 2020 - Wiley Online Library
Abstract Hydrogen peroxide (H2O2) has received increasing attention because it is not only
a mild and environmentally friendly oxidant for organic synthesis and environmental …

Direct decarboxylative Giese reactions

DM Kitcatt, S Nicolle, AL Lee - Chemical Society Reviews, 2022 - pubs.rsc.org
The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Polyoxometalates in solution: speciation under spotlight

NI Gumerova, A Rompel - Chemical Society Reviews, 2020 - pubs.rsc.org
Polyoxometalates (POMs) are a large group of anionic polynuclear metal–oxo clusters with
discrete and chemically modifiable structures. In most aqueous POM solutions, numerous …

Photocatalytic and electrocatalytic generation of hydrogen peroxide: principles, catalyst design and performance

Y Guo, X Tong, N Yang - Nano-Micro Letters, 2023 - Springer
Abstract Hydrogen peroxide (H2O2) is a high-demand organic chemical reagent and has
been widely used in various modern industrial applications. Currently, the prominent method …

Recent advances on high-nuclear polyoxometalate clusters

JC Liu, JW Zhao, C Streb, YF Song - Coordination Chemistry Reviews, 2022 - Elsevier
The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

Directional shunting of photogenerated carriers in POM@ MOF for promoting nitrogen adsorption and oxidation

X Li, L Yang, Q Liu, W Bai, H Li, M Wang… - Advanced …, 2023 - Wiley Online Library
The efficient catalysis of nitrogen (N2) into high‐value N‐containing products plays a crucial
role in the N economic cycle. However, weak N2 adsorption and invalid N2 activation …

A comprehensive review on oxidative desulfurization catalysts targeting clean energy and environment

A Rajendran, T Cui, H Fan, Z Yang, J Feng… - Journal of Materials …, 2020 - pubs.rsc.org
Harvesting clean energy from fuel feedstocks is of paramount significance in the field of
environmental science. In this dynamic area, desulfurization provides a valuable …

Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

AV Anyushin, A Kondinski, TN Parac-Vogt - Chemical Society Reviews, 2020 - pubs.rsc.org
Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …

Multicomponent Self‐Assembly of a Giant Heterometallic Polyoxotungstate Supercluster with Antitumor Activity

JC Liu, JF Wang, Q Han, P Shangguan… - Angewandte …, 2021 - Wiley Online Library
The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

Super atomic clusters: design rules and potential for building blocks of materials

P Jena, Q Sun - Chemical reviews, 2018 - ACS Publications
Atomic clusters, consisting of a few to a few thousand atoms, have emerged over the past 40
years as the ultimate nanoparticles, whose structure and properties can be controlled one …