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Chemical flexibility of atomically precise metal clusters
S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …
Photoluminescent characterization of metal nanoclusters: Basic parameters, methods, and applications
Metal nanoclusters (MNCs) can be synthesized with atomically precise structures and
molecule formulae due to the rapid development of nanocluster science in recent decades …
molecule formulae due to the rapid development of nanocluster science in recent decades …
Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters
Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision
materials and attracted wide interest in recent years. One of the unique properties of such …
materials and attracted wide interest in recent years. One of the unique properties of such …
Elucidating the Near-Infrared Photoluminescence Mechanism of Homometal and Doped M25(SR)18 Nanoclusters
More than a decade of research on the photoluminescence (PL) of classic Au25 (SR) 18 and
its doped nanoclusters (NCs) still leaves many fundamental questions unanswered due to …
its doped nanoclusters (NCs) still leaves many fundamental questions unanswered due to …
Tailoring Carbon Tails of Ligands on Au52(SR)32 Nanoclusters Enhances the Near-Infrared Photoluminescence Quantum Yield from 3.8 to 18.3%
One of the important factors that determine the photoluminescence (PL) properties of gold
nanoclusters pertain to the surface. In this study, four Au52 (SR) 32 nanoclusters that feature …
nanoclusters pertain to the surface. In this study, four Au52 (SR) 32 nanoclusters that feature …
Do**‐Mediated Energy‐Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis
We synthesized a series of MAu12 (dppe) 5Cl2 (MAu12; M= Au, Pd, Pt, Rh, or Ir; dppe= 1, 2‐
bis (diphenylphosphino) ethane), which have icosahedral M@ Au12 superatomic cores, and …
bis (diphenylphosphino) ethane), which have icosahedral M@ Au12 superatomic cores, and …
Sulfide boosting near-unity photoluminescence quantum yield of silver nanocluster
SS Zhang, S Havenridge, C Zhang… - Journal of the …, 2022 - ACS Publications
Silver nanoclusters have emerged as promising candidates for optoelectronic applications,
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …
A review of state of the art in phosphine ligated gold clusters and application in catalysis
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …
which allows the study of structure–property relationships. In addition, they have potential in …
Catalytic Conversion of CO2 over Atomically Precise Gold-Based Cluster Catalysts
X Cai, G Li, W Hu, Y Zhu - ACS Catalysis, 2022 - ACS Publications
There are obstacles with using conventional nanoparticle catalysts for develo** atomic-by-
atom tailoring of active sites in the heterogeneous catalysis field. However, atomically …
atom tailoring of active sites in the heterogeneous catalysis field. However, atomically …