[HTML][HTML] Core level photoelectron spectroscopy of heterogeneous reactions at liquid–vapor interfaces: Current status, challenges, and prospects

R Dupuy, C Richter, B Winter, G Meijer… - The Journal of …, 2021 - pubs.aip.org
Liquid–vapor interfaces, particularly those between aqueous solutions and air, drive
numerous important chemical and physical processes in the atmosphere and in the …

Photoionization of the aqueous phase: clusters, droplets and liquid jets

R Signorell, B Winter - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
This perspective article reviews specific challenges associated with photoemission
spectroscopy of bulk liquid water, aqueous solutions, water droplets and water clusters. The …

Accurate vertical ionization energy and work function determinations of liquid water and aqueous solutions

S Thürmer, S Malerz, F Trinter, U Hergenhahn… - Chemical …, 2021 - pubs.rsc.org
The absolute-scale electronic energetics of liquid water and aqueous solutions, both in the
bulk and at associated interfaces, are the central determiners of water-based chemistry …

Attosecond spectroscopy of size-resolved water clusters

X Gong, S Heck, D Jelovina, C Perry, K Zinchenko… - Nature, 2022 - nature.com
Electron dynamics in water are of fundamental importance for a broad range of phenomena,–
, but their real-time study faces numerous conceptual and methodological challenges …

Hydrogen coupling on platinum using artificial neural network potentials and DFT

PS Rice, ZP Liu, P Hu - The Journal of Physical Chemistry Letters, 2021 - ACS Publications
To date, the understanding of reactions at solid–liquid interfaces has proven challenging,
mainly because of the inaccessible nature of such systems to current experimental …

Photoelectron spectra of alkali metal–ammonia microjets: From blue electrolyte to bronze metal

T Buttersack, PE Mason, RS McMullen, HC Schewe… - Science, 2020 - science.org
Experimental studies of the electronic structure of excess electrons in liquids—archetypal
quantum solutes—have been largely restricted to very dilute electron concentrations. We …

[HTML][HTML] A setup for studies of photoelectron circular dichroism from chiral molecules in aqueous solution

S Malerz, H Haak, F Trinter, AB Stephansen… - Review of Scientific …, 2022 - pubs.aip.org
We present a unique experimental design that enables the measurement of photoelectron
circular dichroism (PECD) from chiral molecules in aqueous solution. The effect is revealed …

Ionization energy of liquid water revisited

CF Perry, P Zhang, FB Nunes, I Jordan… - The journal of …, 2020 - ACS Publications
The ionization energy of liquid water is one of its most fundamental properties, an important
benchmark for first-principles electronic-structure calculations and a crucial reference in the …

Photoelectron spectroscopy from a liquid flatjet

D Stemer, T Buttersack, H Haak, S Malerz… - The Journal of …, 2023 - pubs.aip.org
We demonstrate liquid-jet photoelectron spectroscopy from a flatjet formed by the
im**ement of two micron-sized cylindrical jets of different aqueous solutions. Flatjets …

How to measure work functions from aqueous solutions

M Pugini, B Credidio, I Walter, S Malerz, F Trinter… - Chemical …, 2023 - pubs.rsc.org
The recent application of concepts from condensed-matter physics to photoelectron
spectroscopy (PES) of volatile, liquid-phase systems has enabled the measurement of …