Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Multimetallic-catalyzed C–C bond-forming reactions: from serendipity to strategy

LKG Ackerman-Biegasiewicz… - Journal of the …, 2023 - ACS Publications
The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

Conformational control of cofactors in nature–the influence of protein-induced macrocycle distortion on the biological function of tetrapyrroles

MO Senge, SA MacGowan, JM O'Brien - Chemical Communications, 2015 - pubs.rsc.org
Tetrapyrrole-containing proteins are one of the most fundamental classes of enzymes in
nature and it remains an open question to give a chemical rationale for the multitude of …

Stirring the porphyrin alphabet soup—functionalization reactions for porphyrins

MO Senge - Chemical Communications, 2011 - pubs.rsc.org
Advances in the synthesis of unsymmetrically meso substituted porphyrins are based on the
development of new total syntheses and porphyrin functionalization methods. These …

Inducing open-shell character in porphyrins through surface-assisted phenalenyl π-extension

Q Sun, LM Mateo, R Robles, P Ruffieux… - Journal of the …, 2020 - ACS Publications
Organic open-shell compounds are extraordinarily attractive materials for their use in
molecular spintronics thanks to their long spin-relaxation times and structural flexibility …

Green reduction of reduced graphene oxide with nickel tetraphenyl porphyrin nanocomposite modified electrode for enhanced electrochemical determination of …

S Kubendhiran, S Sakthinathan, SM Chen… - Journal of Colloid and …, 2017 - Elsevier
Nitrobenzene (NB) is widely used in the manufacturing of different types of products and
other aromatic chemicals. Moreover, it is highly toxic and environmental pollutant …

Planar and Curved π-Extended Porphyrins by On-Surface Cyclodehydrogenation

M Baljozović, J Pijeat, S Campidelli… - Journal of the American …, 2024 - ACS Publications
Recent advancements in on-surface synthesis have enabled the reliable and predictable
preparation of atomically precise low-dimensional materials with remarkable properties …

Subporphyrins: a legitimate ring-contracted porphyrin with versatile electronic and optical properties

A Osuka, E Tsurumaki, T Tanaka - Bulletin of the Chemical …, 2011 - academic.oup.com
After a brief survey of our efforts in the development of novel porphyrinoids that include
meso–meso-linked porphyrin arrays, meso-aryl expanded porphyrins, and transition-metal …

Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles

SP Wang, W Lin, X Wang, TY Cen, H **e… - Nature …, 2019 - nature.com
Control of self-assembly is significant to the preparation of supramolecular materials and
illustration of diversities in either natural or artificial systems. Supra-amphiphiles have …