The present review highlights recent developments in the chemistry of sulfur radicals.
Background material essential to the understanding of these developments is briefly …

The electroreductive cleavage of carbon‐chloro bonds has attracted increasing attention
from both environmental and mechanistic points of view over the past decades, taking into …

We describe our efforts to understand the key mechanistic aspects of the previously reported
alkene hydrofunctionalization reactions using 9-mesityl-10-methylacridinium (Mes-Acr+) as …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Au25 (SR) 18 (R=− CH2–CH2–Ph) is a molecule-like nanocluster displaying distinct
electrochemical and optical features. Although it is often taken as an example of a …

Disulfides are involved in a broad range of radical-based synthetic organic and biochemical
transformations. In particular, the reduction of a disulfide to the corresponding radical anion …

We describe a new electrochemical cycle that enables capture and release of carbon
dioxide. The capture agent is benzylthiolate (RS–), generated electrochemically by …

Thioethers are highly prevalent functional groups in organic compounds of natural and
synthetic origin but remain remarkably underexplored as starting materials in desulfurative …

Organosulfides (R–Sn–R) exhibit a high theoretical capacity and low cost, but suffer from
sluggish kinetics and poor reversibility. Here, we demonstrate an effective and universal …

Six-coordinate Pt (IV)-complexes are prominent prodrug candidates for the treatment of
various cancers where, upon two-electron reduction and loss of two axial ligands, they form …