Efficient room-temperature phosphorescence based on a pure organic sulfur-containing heterocycle: folding-induced spin–orbit coupling enhancement

H Liu, Y Gao, J Cao, T Li, Y Wen, Y Ge… - Materials Chemistry …, 2018 - pubs.rsc.org
The development of metal-free room-temperature phosphorescence (RTP) emitters is a very
challenging task, due to one of the most critical issues in pure organic systems: very weak …

Diaryldichalcogenide radical cations

O Mallow, MA Khanfar, M Malischewski, P Finke… - Chemical …, 2015 - pubs.rsc.org
One-electron oxidation of two series of diaryldichalcogenides (C6F5E) 2 (13a–c) and (2, 6-
Mes2C6H3E) 2 (16a–c) was studied (E= S, Se, Te). The reaction of 13a and 13b with AsF5 …

Synthesis and reactivity of the complexes [(dpp-bian)SiCl2] and [(dpp-bian)Si{FeCp(CO)}2(μ-CO)] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)

VA Dodonov, OA Kushnerova, RV Rumyantsev… - Russian Chemical …, 2022 - Springer
Abstract The complex [(dpp-bian) SiCl2](1) was synthesized by the reaction of the free 1, 2-
bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-bian) ligand with Si2Cl6. Despite the …

Chloroaluminate liquid clathrates: Is it the cations or the anions that drive the solubility of aromatics?

R Kore, MK Mishra, UM Gonela… - Industrial & Engineering …, 2020 - ACS Publications
Three chloroaluminate ionic liquids (ILs), triethylammonium tetrachloroaluminate
([HN222][AlCl4]), triethylammonium heptachlorodialuminate ([HN222][Al2Cl7]), and …

Reactions of Thianthrene and 10-Phenylphenothiazine with the Lewis Acids─ Titanium Tetrachloride, Titanium Tetrabromide, Tin (IV) Tetrachloride, or Antimony (V) …

M Roy, W Fu, LM Baldauf, JC Fettinger… - Inorganic …, 2023 - ACS Publications
The oxidation of thianthrene and 10-phenylphenothiazine into cation radicals has been
examined using redox-active Lewis acids. The reaction of titanium (IV) tetrachloride with …

The reaction of phenoxatellurine with single-electron oxidizers revisited

F Mostaghimi, E Lork, I Hong, TL Roemmele… - New Journal of …, 2019 - pubs.rsc.org
The reaction of phenoxatellurine (PT) with the known single-electron oxidizers
AlCl3/CH2Cl2,[NO][SbF6] and [NO][BF4] provided the diamagnetic products [(PT) …

Thio-, seleno-and telluro-ether complexes of aluminium (III) halides: synthesis, structures and properties

K George, M Jura, W Levason, ME Light, G Reid - Dalton Transactions, 2014 - pubs.rsc.org
The reaction of AlCl3 with Me2E (E= S, Se or Te) or nBu2E (E= Se or Te) in CH2Cl2 under
rigorously anhydrous conditions gave the pseudo-tetrahedral complexes [AlCl3 (R2E)]. The …

Boron, aluminium, gallium, indium and thallium

MJ Ingleson - Annual Reports Section" A"(Inorganic Chemistry), 2013 - pubs.rsc.org
This chapter reviews the major advances in the molecular inorganic chemistry of the Group
13 elements published in high impact peer-reviewed journals during 2012. This review is …

Investigation of solvent dynamic effects on the electron self-exchange in two thianthrene couples with large inner reorganization energies

P Choto, K Rasmussen, G Grampp - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
The large structural difference between thianthrene radical cations and their neutral parent
molecules can possibly affect their electron self-exchange reactions. Before this can be …

[PDF][PDF] The Quest of Radical Cations of the Heavier Chalcogenides

F Mostaghimi - 2021 - scholar.archive.org
Sulphur was already known in ancient times and used for example, as described in the
Ebers Papyrus, an ancient Egyptian medical papyrus, in balms for fumigation. Due to its …