Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Chiral recognition by enantioselective liquid chromatography: mechanisms and modern chiral stationary phases

M Lämmerhofer - Journal of Chromatography A, 2010 - Elsevier
An overview of the state-of-the-art in LC enantiomer separation is presented. This tutorial
review is mainly focused on mechanisms of chiral recognition and enantiomer distinction of …

Recent developments on polysaccharide-based chiral stationary phases for liquid-phase separation of enantiomers

B Chankvetadze - Journal of chromatography A, 2012 - Elsevier
This paper summarizes recent developments in the synthesis, application and mechanistic
studies on polysaccharide-based chiral stationary phases (CSPs) for liquid phase …

Chiral recognition in separation sciences. Part I: Polysaccharide and cyclodextrin selectors

GKE Scriba - TrAC Trends in Analytical Chemistry, 2019 - Elsevier
The stereoselective recognition of chiral molecules is an important aspect in nature as the
basis of the interaction of chiral bioactive compounds with their target structures. In …

Recent applications in chiral high performance liquid chromatography: a review

A Cavazzini, L Pasti, A Massi, N Marchetti… - Analytica Chimica Acta, 2011 - Elsevier
The most important and broadly used chiral stationary phases (CSPs) for high performance
liquid chromatography (HPLC) are reviewed. After a short description of the state of the art …

[BOOK][B] Chiroptical spectroscopy: fundamentals and applications

PL Polavarapu - 2016 - taylorfrancis.com
This book details chiroptical spectroscopic methods: electronic circular dichroism (ECD),
optical rotatory dispersion (ORD), vibrational circular dichroism (VCD), and vibrational …

Chiral recognition mechanisms in analytical separation sciences

GKE Scriba - Chromatographia, 2012 - Springer
Chiral recognition phenomena play an important role in nature as well as analytical
separation sciences. In chromatography and capillary electrophoresis, enantiospecific …

Noncovalent interactions in high-performance liquid chromatography enantioseparations on polysaccharide-based chiral selectors

P Peluso, V Mamane, R Dallocchio, A Dessì… - … of Chromatography A, 2020 - Elsevier
Designed more than thirty years ago in order to improve and maximize the discrimination
capability of native polysaccharides, cellulose-and amylose-based selectors have shown …

Natural resourced polysaccharides: Preparation, purification, structural elucidation, structure-activity relationships and regulating intestinal flora, a system review

D Han, L Yang, Q Liang, H Sun, Y Sun, G Yan… - International Journal of …, 2024 - Elsevier
Natural resourced polysaccharides (NRPs), as metabolites synthesized during activity of
organisms, widely present in animal cell membranes or plant and microbial cell walls. NRPs …

The effect of temperature on the separation of enantiomers with coated and covalently immobilized polysaccharide-based chiral stationary phases

I Matarashvili, G Kobidze, A Chelidze, G Dolidze… - … of Chromatography A, 2019 - Elsevier
This article describes our attempt to re-visit the role of temperature in the separation of
enantiomers with polysaccharide-based chiral columns in high-performance liquid …