Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Recent advances of 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) in photocatalytic transformations

TY Shang, LH Lu, Z Cao, Y Liu, WM He… - Chemical …, 2019 - pubs.rsc.org
1, 2, 3, 5-Tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) is a typical donor–acceptor
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …

Alkyl carbon–carbon bond formation by Nickel/Photoredox cross‐coupling

JA Milligan, JP Phelan, SO Badir… - Angewandte Chemie …, 2019 - Wiley Online Library
The union of photoredox and nickel catalysis has resulted in a renaissance in radical
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …

Photoredox-mediated routes to radicals: the value of catalytic radical generation in synthetic methods development

JK Matsui, SB Lang, DR Heitz, GA Molander - ACS catalysis, 2017 - ACS Publications
Photoredox catalysis has experienced a revitalized interest from the synthesis community
during the past decade. For example, photoredox/Ni dual catalysis protocols have been …

4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics

Y Liu, XL Chen, XY Li, SS Zhu, SJ Li… - Journal of the …, 2020 - ACS Publications
2, 4, 5, 6-Tetrakis (3, 6-di-tert-butyl-9 H-carbazol-9-yl) isophthalonitrile (4CzIPN-t Bu) was
developed as a photocatalyst for the phosphorus-radical-initiated cascade cyclization …

sp3 C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

Y Shen, Y Gu, R Martin - Journal of the American Chemical …, 2018 - ACS Publications
Triplet ketone sensitizers are of central importance within the realm of photochemical
transformations. Although the radical-type character of triplet excited states of diaryl ketones …

Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

G Qiu, L Lai, J Cheng, J Wu - Chemical Communications, 2018 - pubs.rsc.org
Recent advances in the sulfonylation of alkenes via the insertion of sulfur dioxide are
summarized. The sulfur dioxide surrogate of DABCO·(SO2) 2 or inorganic sulfites is used in …

Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers

F Le Vaillant, M Garreau, S Nicolai, G Gryn'ova… - Chemical …, 2018 - pubs.rsc.org
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of
alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers …

Heteromultimetallic catalysis for sustainable organic syntheses

MM Lorion, K Maindan, AR Kapdi… - Chemical Society …, 2017 - pubs.rsc.org
Fully complementary bimetallic catalysis has been identified as an increasingly powerful tool
for molecular transformations, which was largely inspired by early examples of sequential …