Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis
MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
Recent advances of 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) in photocatalytic transformations
TY Shang, LH Lu, Z Cao, Y Liu, WM He… - Chemical …, 2019 - pubs.rsc.org
1, 2, 3, 5-Tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) is a typical donor–acceptor
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …
Alkyl carbon–carbon bond formation by Nickel/Photoredox cross‐coupling
JA Milligan, JP Phelan, SO Badir… - Angewandte Chemie …, 2019 - Wiley Online Library
The union of photoredox and nickel catalysis has resulted in a renaissance in radical
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …
Photoredox-mediated routes to radicals: the value of catalytic radical generation in synthetic methods development
Photoredox catalysis has experienced a revitalized interest from the synthesis community
during the past decade. For example, photoredox/Ni dual catalysis protocols have been …
during the past decade. For example, photoredox/Ni dual catalysis protocols have been …
4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics
Y Liu, XL Chen, XY Li, SS Zhu, SJ Li… - Journal of the …, 2020 - ACS Publications
2, 4, 5, 6-Tetrakis (3, 6-di-tert-butyl-9 H-carbazol-9-yl) isophthalonitrile (4CzIPN-t Bu) was
developed as a photocatalyst for the phosphorus-radical-initiated cascade cyclization …
developed as a photocatalyst for the phosphorus-radical-initiated cascade cyclization …
sp3 C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts
Triplet ketone sensitizers are of central importance within the realm of photochemical
transformations. Although the radical-type character of triplet excited states of diaryl ketones …
transformations. Although the radical-type character of triplet excited states of diaryl ketones …
Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions
G Qiu, L Lai, J Cheng, J Wu - Chemical Communications, 2018 - pubs.rsc.org
Recent advances in the sulfonylation of alkenes via the insertion of sulfur dioxide are
summarized. The sulfur dioxide surrogate of DABCO·(SO2) 2 or inorganic sulfites is used in …
summarized. The sulfur dioxide surrogate of DABCO·(SO2) 2 or inorganic sulfites is used in …
Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of
alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers …
alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers …
Heteromultimetallic catalysis for sustainable organic syntheses
Fully complementary bimetallic catalysis has been identified as an increasingly powerful tool
for molecular transformations, which was largely inspired by early examples of sequential …
for molecular transformations, which was largely inspired by early examples of sequential …