Low-Coordinate Iron Hydride Chemistry at an N, N, C-Heteroscorpionate Platform

A Fraker, BN Linn, A McSkimming - Inorganic Chemistry, 2024 - ACS Publications
Locally high-spin iron hydrides are proposed to play a critical role as intermediates in iron–
molybdenum cofactor (FeMoco)-catalyzed N2 fixation. Inspired by these biological systems …

N,N,C Heteroscorpionates as a Platform for Monovalent Ni Chemistry

L Gu, A McSkimming - Organometallics, 2025 - ACS Publications
We report herein the synthesis and characterization of a number of monovalent Ni
complexes bound by a class of N, N, C heteroscorpionate ligands and their derivatives. One …