Ni-catalyzed C–S bond construction and cleavage

S Huang, M Wang, X Jiang - Chemical Society Reviews, 2022 - pubs.rsc.org
Sulfur-containing compounds have attracted considerable interest due to their wide-ranging
applications in pharmaceuticals, agriculture, natural products, and organic materials. The …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Übergangsmetallkatalysierte direkte Arylierungen von (Hetero) Arenen durch C‐H‐Bindungsbruch

L Ackermann, R Vicente, AR Kapdi - Angewandte Chemie, 2009 - Wiley Online Library
Das Gebiet der übergangsmetallkatalysierten direkten Arylierung unter C‐H‐Bindungsbruch
hat in den letzten Jahren eine rasante Entwicklung erfahren, was dazu führte, dass sich …

Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Synthesis and applications of sodium sulfinates (RSO 2 Na): a powerful building block for the synthesis of organosulfur compounds

RJ Reddy, AH Kumari - RSC advances, 2021 - pubs.rsc.org
This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …

Carboxylate-assisted transition-metal-catalyzed C− H bond functionalizations: mechanism and scope

L Ackermann - Chemical reviews, 2011 - ACS Publications
The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners

R Jana, TP Pathak, MS Sigman - Chemical reviews, 2011 - ACS Publications
Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Transition‐metal‐catalyzed direct arylation of (hetero) arenes by C H bond cleavage

L Ackermann, R Vicente… - Angewandte Chemie …, 2009 - Wiley Online Library
The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Functionalized olefin cross-coupling to construct carbon–carbon bonds

JC Lo, J Gui, Y Yabe, CM Pan, PS Baran - Nature, 2014 - nature.com
Abstract Carbon–carbon (C–C) bonds form the backbone of many important molecules,
including polymers, dyes and pharmaceutical agents. The development of new methods to …

Recent advances in the synthesis of aryl nitrile compounds

G Yan, Y Zhang, J Wang - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Aryl nitriles are widely found in natural products, pharmaceuticals, agrochemicals, dyes, and
herbicides. Moreover, because the cyano group can be easily converted into various …