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Phosphate ester hydrolysis: metal complexes as purple acid phosphatase and phosphotriesterase analogues
LR Gahan, SJ Smith, A Neves… - European journal of …, 2009 - Wiley Online Library
This microreview describes the structures and properties of a number of bimetallic
complexes designed as both structural and functional mimics of the active sites of some …
complexes designed as both structural and functional mimics of the active sites of some …
Synthesis, structure and interactions with DNA of novel tetranuclear,[Mn4 (II/II/II/IV)] mixed valence complexes
A Dimitrakopoulou, C Dendrinou-Samara… - Journal of Inorganic …, 2008 - Elsevier
Reaction of Mn (II) with phenoxyalkanoic acids and di-2-pyridyl ketone oxime (Hpko) leads
to neutral tetranuclear complexes of the general formula Mn4 (O)(pko) 4 (phenoxyalkanoato) …
to neutral tetranuclear complexes of the general formula Mn4 (O)(pko) 4 (phenoxyalkanoato) …
A short review on the structure–function relationship of artificial catecholase/tyrosinase and nuclease activities of Cu-complexes
R Silavi, A Divsalar, AA Saboury - Journal of Biomolecular …, 2012 - Taylor & Francis
The synthesis of metal complexes has vastly increased the scope of research for many
scientists during the two last decades. Among these compounds, artificial tyrosinases …
scientists during the two last decades. Among these compounds, artificial tyrosinases …
Iron and copper complexes with antioxidant activity as inhibitors of the metastatic potential of glioma cells
Gliomas are the most common type of primary brain tumors, presenting high mortality and
recurrence rates that highlight the need for the development of more efficient therapies. In …
recurrence rates that highlight the need for the development of more efficient therapies. In …
Influence of ligand rigidity and ring substitution on the structural and electronic behavior of trivalent iron and gallium complexes with asymmetric tridentate ligands
C Imbert, HP Hratchian, M Lanznaster… - Inorganic …, 2005 - ACS Publications
Species 1− 6 are [MIII (L) 2] ClO4 complexes formed with the PhO-− CH N− CH2− Py
imines,(LI)-and (L tBuI)-, and PhO-− CH2− NH− CH2− Py amines,(LA)-and (L tBuA)-, in …
imines,(LI)-and (L tBuI)-, and PhO-− CH2− NH− CH2− Py amines,(LA)-and (L tBuA)-, in …
Synthesis, crystal structure, nuclease and in vitro antitumor activities of a new mononuclear copper (II) complex containing a tripodal N3O ligand
C Fernandes, GL Parrilha, JA Lessa, LJM Santiago… - Inorganica chimica …, 2006 - Elsevier
We present here the synthesis, crystal structure, electrochemical behavior, spectroscopic
properties (FT-IR, UV–Vis and EPR), nuclease and in vitro antitumor activities against …
properties (FT-IR, UV–Vis and EPR), nuclease and in vitro antitumor activities against …
Synthesis, characterization, hydrolase and catecholase activity of a dinuclear iron (III) complex: Catalytic promiscuity
TP Camargo, FF Maia, C Chaves, B de Souza… - Journal of Inorganic …, 2015 - Elsevier
Herein, we report the synthesis and characterization of the new di-iron (III) complex
[(bbpmp)(H 2 O)(Cl) Fe III (μ-O phenoxo) Fe III (H 2 O) Cl)] Cl (1), with the symmetrical ligand …
[(bbpmp)(H 2 O)(Cl) Fe III (μ-O phenoxo) Fe III (H 2 O) Cl)] Cl (1), with the symmetrical ligand …
A new mixed-valence Mn (II) Mn (III) compound with catalase and superoxide dismutase activities
RO Costa, SS Ferreira, CA Pereira, JR Harmer… - Frontiers in …, 2018 - frontiersin.org
The synthesis, X-ray molecular structure, physico-chemical characterization and dual
antioxidant activity (catalase and superoxide dismutase) of a new polymeric mixed valence …
antioxidant activity (catalase and superoxide dismutase) of a new polymeric mixed valence …
Synthesis and characterization of Fe III (μ-OH) Zn II complexes: effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a …
GA dos Santos Silva, AL Amorim, B De Souza… - Dalton …, 2017 - pubs.rsc.org
The synthesis and characterization of three ligands and their respective heterobinuclear
FeIIIZnII complexes were carried out, with the goal of mimicking the active site of purple acid …
FeIIIZnII complexes were carried out, with the goal of mimicking the active site of purple acid …
Two Plus Four Equals Three–Iron (II)/Iron (IV) Comproportionation as an Additional Pathway for Iron (IV)-Oxido Reactions
NSW Lindlar né Jonasson, A Menke, L Senft… - Inorganic …, 2025 - ACS Publications
Iron enzymes are ubiquitous in nature. In particular, enzymes with iron–oxygen cofactors as
active sites perform a vast variety of reactions. Both iron (III)-hydroxido and iron (IV)-oxido …
active sites perform a vast variety of reactions. Both iron (III)-hydroxido and iron (IV)-oxido …