Phosphate ester hydrolysis: metal complexes as purple acid phosphatase and phosphotriesterase analogues

LR Gahan, SJ Smith, A Neves… - European journal of …, 2009 - Wiley Online Library
This microreview describes the structures and properties of a number of bimetallic
complexes designed as both structural and functional mimics of the active sites of some …

Synthesis, structure and interactions with DNA of novel tetranuclear,[Mn4 (II/II/II/IV)] mixed valence complexes

A Dimitrakopoulou, C Dendrinou-Samara… - Journal of Inorganic …, 2008 - Elsevier
Reaction of Mn (II) with phenoxyalkanoic acids and di-2-pyridyl ketone oxime (Hpko) leads
to neutral tetranuclear complexes of the general formula Mn4 (O)(pko) 4 (phenoxyalkanoato) …

A short review on the structure–function relationship of artificial catecholase/tyrosinase and nuclease activities of Cu-complexes

R Silavi, A Divsalar, AA Saboury - Journal of Biomolecular …, 2012 - Taylor & Francis
The synthesis of metal complexes has vastly increased the scope of research for many
scientists during the two last decades. Among these compounds, artificial tyrosinases …

Iron and copper complexes with antioxidant activity as inhibitors of the metastatic potential of glioma cells

JF Guerreiro, MAGB Gomes, F Pagliari, J Jansen… - RSC …, 2020 - pubs.rsc.org
Gliomas are the most common type of primary brain tumors, presenting high mortality and
recurrence rates that highlight the need for the development of more efficient therapies. In …

Influence of ligand rigidity and ring substitution on the structural and electronic behavior of trivalent iron and gallium complexes with asymmetric tridentate ligands

C Imbert, HP Hratchian, M Lanznaster… - Inorganic …, 2005 - ACS Publications
Species 1− 6 are [MIII (L) 2] ClO4 complexes formed with the PhO-− CH N− CH2− Py
imines,(LI)-and (L tBuI)-, and PhO-− CH2− NH− CH2− Py amines,(LA)-and (L tBuA)-, in …

Synthesis, crystal structure, nuclease and in vitro antitumor activities of a new mononuclear copper (II) complex containing a tripodal N3O ligand

C Fernandes, GL Parrilha, JA Lessa, LJM Santiago… - Inorganica chimica …, 2006 - Elsevier
We present here the synthesis, crystal structure, electrochemical behavior, spectroscopic
properties (FT-IR, UV–Vis and EPR), nuclease and in vitro antitumor activities against …

Synthesis, characterization, hydrolase and catecholase activity of a dinuclear iron (III) complex: Catalytic promiscuity

TP Camargo, FF Maia, C Chaves, B de Souza… - Journal of Inorganic …, 2015 - Elsevier
Herein, we report the synthesis and characterization of the new di-iron (III) complex
[(bbpmp)(H 2 O)(Cl) Fe III (μ-O phenoxo) Fe III (H 2 O) Cl)] Cl (1), with the symmetrical ligand …

A new mixed-valence Mn (II) Mn (III) compound with catalase and superoxide dismutase activities

RO Costa, SS Ferreira, CA Pereira, JR Harmer… - Frontiers in …, 2018 - frontiersin.org
The synthesis, X-ray molecular structure, physico-chemical characterization and dual
antioxidant activity (catalase and superoxide dismutase) of a new polymeric mixed valence …

Synthesis and characterization of Fe III (μ-OH) Zn II complexes: effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a …

GA dos Santos Silva, AL Amorim, B De Souza… - Dalton …, 2017 - pubs.rsc.org
The synthesis and characterization of three ligands and their respective heterobinuclear
FeIIIZnII complexes were carried out, with the goal of mimicking the active site of purple acid …

Two Plus Four Equals Three–Iron (II)/Iron (IV) Comproportionation as an Additional Pathway for Iron (IV)-Oxido Reactions

NSW Lindlar né Jonasson, A Menke, L Senft… - Inorganic …, 2025 - ACS Publications
Iron enzymes are ubiquitous in nature. In particular, enzymes with iron–oxygen cofactors as
active sites perform a vast variety of reactions. Both iron (III)-hydroxido and iron (IV)-oxido …