The role of local structure in dynamical arrest

CP Royall, SR Williams - Physics Reports, 2015 - Elsevier
Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-
range structural order. At the level of two-body structural correlations, glassformers show no …

Recent crucial discoveries and perspectives on crystal nucleation in supercooled liquids and oxide glasses

LR Rodrigues, MHR Acosta, ED Zanotto - Progress in Materials Science, 2023 - Elsevier
Due to their measurable crystallization kinetics, oxide glass-formers are adequate systems
for evaluating theoretical approaches to describe and predict crystal nucleation dynamics …

Bond orientational order in liquids: Towards a unified description of water-like anomalies, liquid-liquid transition, glass transition, and crystallization: Bond orientational …

H Tanaka - The European Physical Journal E, 2012 - Springer
There are at least three fundamental states of matter, depending upon temperature and
pressure: gas, liquid, and solid (crystal). These states are separated by first-order phase …

Polymer glass formation: Role of activation free energy, configurational entropy, and collective motion

WS Xu, JF Douglas, ZY Sun - Macromolecules, 2021 - ACS Publications
We provide a perspective on polymer glass formation, with an emphasis on models in which
the fluid entropy and collective particle motion dominate the theoretical description and data …

Cracking the Kauzmann paradox

RS Welch, ED Zanotto, CJ Wilkinson, DR Cassar… - Acta Materialia, 2023 - Elsevier
The Kauzmann paradox and associated Kauzmann temperature are two of the most widely
debated topics in glass science over the past eighty years. Both conceptualized by Walter …

Structural origin of dynamic heterogeneity in three-dimensional colloidal glass formers and its link to crystal nucleation

T Kawasaki, H Tanaka - Journal of Physics: Condensed Matter, 2010 - iopscience.iop.org
The physical understanding of glass transition remains a major challenge of physics and
materials science. Among various glass-forming liquids, a colloidal liquid interacting with …

Recent developments in the experimental investigations of relaxations in pharmaceuticals by dielectric techniques at ambient and elevated pressure

K Grzybowska, S Capaccioli, M Paluch - Advanced drug delivery reviews, 2016 - Elsevier
In recent years, there is a growing interest in improving the physicochemical stability of
amorphous pharmaceutical solids due to their very promising applications to manufacture …

String-like cooperative motion in homogeneous melting

H Zhang, M Khalkhali, Q Liu, JF Douglas - The Journal of chemical …, 2013 - pubs.aip.org
Despite the fundamental nature and practical importance of melting, there is still no
generally accepted theory of this ubiquitous phenomenon. Even the earliest simulations of …

Glass transition of the monodisperse gaussian core model

A Ikeda, K Miyazaki - Physical review letters, 2011 - APS
We numerically investigate the dynamical properties of the one-component Gaussian core
model in supercooled states. We find that nucleation is increasingly suppressed with …

Lifetimes and lengthscales of structural motifs in a model glassformer

A Malins, J Eggers, H Tanaka, CP Royall - Faraday discussions, 2013 - pubs.rsc.org
We use a newly-developed method to identify local structural motifs in a popular model
glassformer, the Kob–Andersen binary Lennard-Jones mixture. By measuring the lifetimes of …