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Polycyclic aromatic chains on metals and insulating layers by repetitive [3+ 2] cycloadditions
The vast potential of organic materials for electronic, optoelectronic and spintronic devices
entails substantial interest in the fabrication of π-conjugated systems with tailored …
entails substantial interest in the fabrication of π-conjugated systems with tailored …
Structure and Reactivity of the Ionic Liquid [C1C1Im][Tf2N] on Cu(111)
R Adhikari, S Massicot, L Fromm, T Talwar, A Gezmis… - Topics in …, 2023 - Springer
We studied the adsorption and reaction behavior of the ionic liquid (IL) 1, 3-
dimethylimidazolium bis [(trifluoromethyl) sulfonyl] imide ([C1C1Im][Tf2N]) on Cu (111) using …
dimethylimidazolium bis [(trifluoromethyl) sulfonyl] imide ([C1C1Im][Tf2N]) on Cu (111) using …
Roles of precursor conformation and adatoms in Ullmann coupling: An inverted porphyrin on Cu (111)
Surface diffusion, molecular conformation, and on-surface coupling reactions are key
processes for building tailored molecular nanostructures such as graphene nanoribbons …
processes for building tailored molecular nanostructures such as graphene nanoribbons …
Reassessing the adsorption behavior and on-surface reactivity of a brominated porphyrin on Cu (111)
A Ceccatto dos Santos… - The Journal of …, 2021 - ACS Publications
On-surface coupling reactions and molecular conformation are essential processes for
building tailored functional molecular nanostructures. Here, we study the thermal …
building tailored functional molecular nanostructures. Here, we study the thermal …
Controlling the Self‐Metalation Rate of Tetraphenylporphyrins on Cu (111) via Cyano Functionalization
M Lepper, J Köbl, L Zhang, M Meusel… - Angewandte Chemie …, 2018 - Wiley Online Library
The reaction rate of the self‐metalation of free‐base tetraphenylporphyrins (TPPs) on Cu
(111) increases with the number of cyano groups (n= 0, 1, 2, 4) attached at the para …
(111) increases with the number of cyano groups (n= 0, 1, 2, 4) attached at the para …
Cyano-functionalized porphyrins on Cu (111) from one-dimensional wires to two-dimensional molecular frameworks: on the role of Co-deposited metal atoms
A Ceccatto dos Santos… - Chemistry of …, 2020 - ACS Publications
Metal adatoms play a key role in surface diffusion, adsorption conformation, and self-
assembly of porphyrin molecules on metal surfaces. Herein, we study the specific influence …
assembly of porphyrin molecules on metal surfaces. Herein, we study the specific influence …
Electric field control of molecular charge state in a single-component 2D organic nanoarray
Quantum dots (QD) with electric-field-controlled charge state are promising for electronics
applications, eg, digital information storage, single-electron transistors, and quantum …
applications, eg, digital information storage, single-electron transistors, and quantum …
Coverage-dependent structural transformation of cyano-functionalized porphyrin networks on Au (111) via addition of cobalt atoms
BD Baker Cortés, N Schmidt, M Enache… - The Journal of …, 2019 - ACS Publications
The self-assembly process of a cobalt-porphyrin derivative (Co-TCNPP) containing
cyanophenyl substituents at all four meso positions on Au (111) was studied by means of …
cyanophenyl substituents at all four meso positions on Au (111) was studied by means of …
Supramolecular ordering and reactions of a chlorophenyl porphyrin on Ag (111)
Surface-assisted Ullmann-type coupling reactions are a potential bottom-up approach for
building tailored low-dimensional materials with novel physical and chemical properties. In …
building tailored low-dimensional materials with novel physical and chemical properties. In …
Formation of highly ordered molecular porous 2D networks from cyano‐functionalized porphyrins on Cu (111)
R Adhikari, G Siglreithmaier, M Gurrath… - … A European Journal, 2020 - Wiley Online Library
We investigated the adsorption of three related cyano‐functionalized tetraphenyl porphyrin
derivatives on Cu (111) by scanning tunneling microscopy (STM) in ultra‐high vacuum …
derivatives on Cu (111) by scanning tunneling microscopy (STM) in ultra‐high vacuum …