Ynamides are among the most powerful building blocks in organic synthesis and have
become invaluable starting materials for the construction of multifunctional compounds and …

In this review we present the transformations that have been developed with ynamides and
free radicals. These reactions involve carbon‐, heteroatom‐or even metalloid‐centered …

Using ynamides as readily available starting materials, a single step can generate highly
reactive ketenimines, which can then undergo a variety of transformations. The choice of the …

The development of versatile catalyst systems and new transformations for the utilization of
carbon dioxide (CO2) is of great interest and significance. This Personal Account reviews …

Ynamides are fascinating small molecules with complementary reactivities under radical,
ionic, and metal-catalyzed conditions. We report herein synthetic and DFT investigations of …

Ynamides have recently evolved as remarkably reactive and versatile building blocks for
chemical synthesis. The development of efficient and robust methods for their preparation …

A photochemical dual‐catalytic cross‐coupling to form alkynyl sulfides via C (sp)− S bond
formation is described. The cross‐coupling of thiols and bromoalkynes is promoted by a …

Form a green and sustainable chemistry point of view, cross-dehydrogenative coupling (or
oxidative cross-coupling) reactions have been recognized as environmentally sustainable …

Fluorinated pyridones are an important scaffold displaying relevant biological activities.
Efficient assembly strategies of pyridones are transition metal-catalyzed C–H annulations …

The palladium‐catalyzed silylcyanation of ynamides is described. This reaction is fully
regioselective, delivering tetrasubstituted 2‐aminoacrylonitriles derivatives exclusively …