Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
Crystalline mate for structure elucidation of organic molecules
JG Song, J Zheng, RJ Wei, YL Huang, J Jiang… - Chem, 2024 - cell.com
Single-crystal X-ray diffraction (SCXRD) analysis is the most definitive structure
determination method, yet it hinges upon the success of crystal growth and that can …
determination method, yet it hinges upon the success of crystal growth and that can …
Advanced crystallography for structure determination of natural products
JG Song, WC Ye, Y Wang - Natural Product Reports, 2025 - pubs.rsc.org
Covering: up to 2025Crystallographic analysis has become the most reliable method for
elucidating the structures of natural products, as it can provide absolute configurations with …
elucidating the structures of natural products, as it can provide absolute configurations with …
Room-temperature phosphorescence and dual-emission behavior of simple biphenyl derivatives unlocked by intermolecular interactions with cyclic silver pyrazolate
The complexation of 4, 4′-halogen-substituted biphenyls (BPs) with a trinuclear silver (I) 3,
5-bis (trifluoromethyl) pyrazolate adduct ([AgL] 3) is observed in the solution and solid states …
5-bis (trifluoromethyl) pyrazolate adduct ([AgL] 3) is observed in the solution and solid states …
Substituents' Effect on the Photophysics of Trinuclear Copper (I) and Silver (I) Pyrazolate–Phosphine Cages
KF Baranova, AA Titov, JR Shakirova… - Inorganic …, 2024 - ACS Publications
A series of structurally similar trinuclear macrocyclic copper (I) and silver (I) pyrazolate
complexes bearing various short-bite diphosphine R2PCH (R′) PR2 ligands are reported …
complexes bearing various short-bite diphosphine R2PCH (R′) PR2 ligands are reported …
Synthesis of luminescent coumarin-substituted phosphinoamide-bridged polynuclear gold (I) metallacycles and reactivity studies
Herein, we present the first report of coumarin-based phosphinoamine ligands [CoumPNH]
and their gold (I) complexes. The deprotonation and chloride abstraction from …
and their gold (I) complexes. The deprotonation and chloride abstraction from …
Acetylene and terminal alkyne complexes of copper (I) supported by fluorinated pyrazolates: Syntheses, structures, and transformations
Trinuclear {μ-[3, 5-(CF3) 2Pz] Cu} 3 reacts with acetylene to produce the 2: 1 copper (I)
acetylene complex, Cu4 (μ-[3, 5-(CF3) 2Pz]) 4 (μ-HCCH) 2. Related Cu4 (μ-[4-Br-3, 5-(CF3) …
acetylene complex, Cu4 (μ-[3, 5-(CF3) 2Pz]) 4 (μ-HCCH) 2. Related Cu4 (μ-[4-Br-3, 5-(CF3) …
Emissive silver (i) cyclic trinuclear complexes with aromatic amine donor pyrazolate derivatives: Way to efficiency
3-Trifluoromethyl-pyrazoles containing strong fluorophore groups: triphenylamine (TPAPz)
and carbazole (CarbPz), and their trinuclear silver (I) complexes are found to be emissive in …
and carbazole (CarbPz), and their trinuclear silver (I) complexes are found to be emissive in …
In situ studies of reversible solid–gas reactions of ethylene responsive silver pyrazolates
Solid–gas reactions and in situ powder X-ray diffraction investigations of trinuclear silver
complexes {[3, 4, 5-(CF3) 3Pz] Ag} 3 and {[4-Br-3, 5-(CF3) 2Pz] Ag} 3 supported by highly …
complexes {[3, 4, 5-(CF3) 3Pz] Ag} 3 and {[4-Br-3, 5-(CF3) 2Pz] Ag} 3 supported by highly …
Mechanistic study in azide-alkyne cycloaddition (CuAAC) catalyzed by bifunctional trinuclear copper (I) pyrazolate complex: Shift in rate-determining step
Trinuclear copper (I) pyrazolate [Cu (3, 5-(CF 3) 2 Pz)] 3 was employed in a mechanistic
study of azide-alkyne cycloaddition (CuAAC). It was shown that the copper complex …
study of azide-alkyne cycloaddition (CuAAC). It was shown that the copper complex …