[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

On the structure of γ-Al2O3

R Prins - Journal of Catalysis, 2020 - Elsevier
The structure of γ-Al 2 O 3, the most important catalyst support, is still under discussion;
especially the positions of the Al 3+ cations and vacancies are debated. One model …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Catalyst support effects on hydrogen spillover

W Karim, C Spreafico, A Kleibert, J Gobrecht… - Nature, 2017 - nature.com
Hydrogen spillover is the surface migration of activated hydrogen atoms from a metal
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …

Plasma-Catalytic Methanol Synthesis from CO2 Hydrogenation over a Supported Cu Cluster Catalyst: Insights into the Reaction Mechanism

Z Cui, S Meng, Y Yi, A Jafarzadeh, S Li, EC Neyts… - ACS …, 2022 - ACS Publications
Plasma-catalytic CO2 hydrogenation for methanol production is gaining increasing interest,
but our understanding of its reaction mechanism remains primitive. We present a combined …

Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2

S Zhang, ZQ Huang, Y Ma, W Gao, J Li, F Cao… - Nature …, 2017 - nature.com
Identification on catalytic sites of heterogeneous catalysts at atomic level is important to
understand catalytic mechanism. Surface engineering on defects of metal oxides can …

Catalyst deactivation via decomposition into single atoms and the role of metal loading

ED Goodman, AC Johnston-Peck, EM Dietze… - Nature …, 2019 - nature.com
In the high-temperature environments needed to perform catalytic processes, supported
precious metal catalysts lose their activity severely over time. Generally, loss of catalytic …

Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina

EJ Peterson, AT DeLaRiva, S Lin, RS Johnson… - Nature …, 2014 - nature.com
Catalysis by single isolated atoms of precious metals has attracted much recent interest, as it
promises the ultimate in atom efficiency. Most previous reports are on reducible oxide …

On the Role of Hydroxyl Groups on Cu/Al2O3 in CO2 Hydrogenation

X Song, C Yang, X Li, Z Wang, C Pei, ZJ Zhao… - ACS …, 2022 - ACS Publications
Understanding the nature of adsorbates and intermediates on catalytic surfaces is critical for
the development of highly efficient systems for CO2 conversion. However, the role of …

The tailored role of “defect” sites on γ-alumina: A key to yield an efficient methane dry reforming catalyst with superior nickel utilization

Y Zhang, Y Zu, D He, J Liang, L Zhu, Y Mei… - Applied Catalysis B …, 2022 - Elsevier
Strong metal support interaction between Ni and γ-Al 2 O 3, resulted from the excessive
hydroxyl groups on the Al 2 O 3 support, has restricted Ni utilization in the traditional Ni/Al 2 …