[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …
catalysts because they offer many advantages over their homogeneous counterparts such …
On the structure of γ-Al2O3
R Prins - Journal of Catalysis, 2020 - Elsevier
The structure of γ-Al 2 O 3, the most important catalyst support, is still under discussion;
especially the positions of the Al 3+ cations and vacancies are debated. One model …
especially the positions of the Al 3+ cations and vacancies are debated. One model …
Heterolytic Dissociation of H2 in Heterogeneous Catalysis
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …
Catalyst support effects on hydrogen spillover
W Karim, C Spreafico, A Kleibert, J Gobrecht… - Nature, 2017 - nature.com
Hydrogen spillover is the surface migration of activated hydrogen atoms from a metal
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …
Plasma-Catalytic Methanol Synthesis from CO2 Hydrogenation over a Supported Cu Cluster Catalyst: Insights into the Reaction Mechanism
Plasma-catalytic CO2 hydrogenation for methanol production is gaining increasing interest,
but our understanding of its reaction mechanism remains primitive. We present a combined …
but our understanding of its reaction mechanism remains primitive. We present a combined …
Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2
S Zhang, ZQ Huang, Y Ma, W Gao, J Li, F Cao… - Nature …, 2017 - nature.com
Identification on catalytic sites of heterogeneous catalysts at atomic level is important to
understand catalytic mechanism. Surface engineering on defects of metal oxides can …
understand catalytic mechanism. Surface engineering on defects of metal oxides can …
Catalyst deactivation via decomposition into single atoms and the role of metal loading
In the high-temperature environments needed to perform catalytic processes, supported
precious metal catalysts lose their activity severely over time. Generally, loss of catalytic …
precious metal catalysts lose their activity severely over time. Generally, loss of catalytic …
Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
Catalysis by single isolated atoms of precious metals has attracted much recent interest, as it
promises the ultimate in atom efficiency. Most previous reports are on reducible oxide …
promises the ultimate in atom efficiency. Most previous reports are on reducible oxide …
On the Role of Hydroxyl Groups on Cu/Al2O3 in CO2 Hydrogenation
Understanding the nature of adsorbates and intermediates on catalytic surfaces is critical for
the development of highly efficient systems for CO2 conversion. However, the role of …
the development of highly efficient systems for CO2 conversion. However, the role of …
The tailored role of “defect” sites on γ-alumina: A key to yield an efficient methane dry reforming catalyst with superior nickel utilization
Y Zhang, Y Zu, D He, J Liang, L Zhu, Y Mei… - Applied Catalysis B …, 2022 - Elsevier
Strong metal support interaction between Ni and γ-Al 2 O 3, resulted from the excessive
hydroxyl groups on the Al 2 O 3 support, has restricted Ni utilization in the traditional Ni/Al 2 …
hydroxyl groups on the Al 2 O 3 support, has restricted Ni utilization in the traditional Ni/Al 2 …