The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

Transition metal-catalyzed cross-coupling reactions of organic electrophiles and
organometallic reagents have emerged as a tremendously powerful synthetic tool, and the …

Transition metal catalysts, particularly those derived from the group VIII− X metals, display
remarkable efficiency for the formation of carbon− carbon and carbon− heteroatom bonds …

C–S bond activation, cleavage and transformations by means of transition metal compounds
have recently become more and more important in the petroleum industry and synthetic …

Iron‐catalyzed cross‐coupling reactions have, over the past years, developed to maturity
and today are an integral part of the organic chemist's toolkit. They benefit from low costs …

Cross-couplings of alkyl halides and organometallic species based on single electron
transfer using Ni and Fe catalyst systems have been studied extensively, and separately, for …

Transition metal-catalyzed C–C bond formations have been well studied over the last four
decades. An improved mechanistic understanding of such reactions has helped chemists to …

A series of unprecedented organoiron complexes of the formal oxidation states− 2, 0,+ 1,+ 2,
and+ 3 is presented, which are largely devoid of stabilizing ligands and, in part, also …

Sulfinic acids and their salts have recently emerged as versatile coupling partners to
efficiently access a wide variety of hetero-and carbocyclic compounds, under relatively mild …