Cathodic corrosion of metal electrodes—how to prevent it in electroorganic synthesis

T Wirtanen, T Prenzel, JP Tessonnier… - Chemical …, 2021 - ACS Publications
The critical aspects of the corrosion of metal electrodes in cathodic reductions are covered.
We discuss the involved mechanisms including alloying with alkali metals, cathodic etching …

[HTML][HTML] Cathodic corrosion: 21st century insights into a 19th century phenomenon

TJP Hersbach, MTM Koper - Current Opinion in Electrochemistry, 2021 - Elsevier
Cathodic corrosion is an enigmatic electrochemical process that etches metallic electrodes
at potentials below 0 Volt versus the normal hydrogen electrode. Though this phenomenon …

Thermally regenerative copper nanoslurry flow batteries for heat-to-power conversion with low-grade thermal energy

S Maye, HH Girault, P Peljo - Energy & Environmental Science, 2020 - pubs.rsc.org
Low-grade heat (below 200° C) is available in vast quantities from industry, or from standard
roof-top solar thermal collectors. However, the production of electric power from these heat …

Electrochemical synthesis of catalytic materials for energy catalysis

D Gao, H Li, P Wei, Y Wang, G Wang, X Bao - Chinese Journal of Catalysis, 2022 - Elsevier
Electrocatalysis is a process dealing with electrochemical reactions in the interconversion of
chemical energy and electrical energy. Precise synthesis of catalytically active …

Top-Down Synthesis of Nanostructured Platinum–Lanthanide Alloy Oxygen Reduction Reaction Catalysts: PtxPr/C as an Example

J Fichtner, B Garlyyev, S Watzele… - … Applied Materials & …, 2019 - ACS Publications
The oxygen reduction reaction (ORR) is of great interest for future sustainable energy
conversion and storage, especially concerning fuel cell applications. The preparation of …

Tailoring the oxygen reduction activity of Pt nanoparticles through surface defects: a simple top-down approach

J Fichtner, S Watzele, B Garlyyev, RM Kluge… - ACS …, 2020 - ACS Publications
Results from Pt model catalyst surfaces have demonstrated that surface defects, in particular
surface concavities, can improve the oxygen reduction reaction (ORR) kinetics. It is …

Alkali metal cation effects in structuring Pt, Rh, and Au surfaces through cathodic corrosion

TJP Hersbach, IT McCrum… - … applied materials & …, 2018 - ACS Publications
Cathodic corrosion is an electrochemical etching process that alters metallic surfaces by
creating nanoparticles and a variety of etching features. Because these features typically …

Metal deposition and electrocatalysis for elucidating structural changes of gold electrodes during cathodic corrosion

MM Elnagar, LA Kibler, T Jacob - Green Chemistry, 2023 - pubs.rsc.org
Several electrochemical conversion reactions occur under high cathodic currents, where
electrocatalysts can experience substantial alterations in their surface structure through …

Synthesis of nanoparticles by spark discharge as a facile and versatile technique of preparing highly conductive Pt nano-ink for printed electronics

AA Efimov, PV Arsenov, VI Borisov, AI Buchnev… - Nanomaterials, 2021 - mdpi.com
A cost-effective, scalable and versatile method of preparing nano-ink without hazardous
chemical precursors is a prerequisite for widespread adoption of printed electronics …

Platinum hydride formation during cathodic corrosion in aqueous solutions

TJP Hersbach, AT Garcia-Esparza, S Hanselman… - Nature Materials, 2025 - nature.com
Cathodic corrosion is an electrochemical phenomenon that etches metals at moderately
negative potentials. Although cathodic corrosion probably occurs by forming a metal …