Recent years have witnessed remarkable advances in radical reactions involving main‐
group metal complexes. This includes the isolation and detailed characterization of main …

Ligands are innocent when they allow oxidation states of the central atoms to be defined. A
noninnocent (or redox) ligand is a ligand in a metal complex where the oxidation state is not …

A new monoiminoacenaphthenone 3, 5-(CF3) 2C6H3-mian (complex 2) was synthesized
and further exploited, along with the already known monoiminoacenaphthenone dpp-mian …

Complexes [(dpp-BIAN) 0CoIII2]· MeCN (I) and [(Py) 2CoI2](II) were synthesized by the
reaction between cobalt (II) iodide and 1, 2-bis (2, 6-diisopropylphenylimino) acenaphthene …

A series of cationic Au (I)-BIAN/MIAN complexes, namely [(PPh3) Au (L)] OTf, where L= dpp-
bian (1), dpp-mian (2), 2-Me-Ph-bian (3) and 4-Me-Ph-bian (4), has been prepared. All …

Redox properties of monoiminoacenaphthenes (MIANs) were studied using various
electrochemical techniques. The potential values obtained were used for calculating the …

The reaction of the redox active 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-
BIAN) and iron (II) iodide in acetonitrile led to a new complex [(dpp-BIAN) FeIII2](1) …

During the partial hydrolysis of metal complexes with the mono-imino-acenaphthen-1-olate
(R-mian) dianion, the nitrogen atom is protonated at the first stage, while the metal-ligand …

The paper describes the influence of a series of bis (arylimino) acenaphthenes (R-bian) and
mono (arylimino) acenapthenones (R-mian) in the aerobic oxidation of cumene. The imines …

Abstract The reaction of Dpp-Bian (Dpp-Bian is 1, 2-bis [(2, 6-diisopropylphenyl) imino]
acenaphthene) with one equivalent of iodine and an excess of metallic tin affords …