Catalytic Continuous Reductive Amination with Hydrogen in Flow Reactors

J Zhang, Y Xu, Y Li, J Yin, J Zhang - ChemCatChem, 2024 - Wiley Online Library
Reductive amination with hydrogen is a green and atom‐efficient method to construct
amines from accessible aldehydes and ketones. Flow reactors, with superior mass and heat …

Stable and Continuous Production of Amines via Reductive Amination in a Green Switchable Solvent System with Efficient Water Removal

TB Riemer, P Lapac, D Vogt… - … Sustainable Chemistry & …, 2023 - ACS Publications
We present highly selective Rh-catalyzed reductive amination (RA) with integrated recycling
of the homogeneous catalyst via a thermomorphic multiphase system (TMS) in a continuous …

Selective Multifunctional Aliphatic Amine Synthesis: Unraveling Universal Control Strategies in Catalytic Reductive Amination of Biobased α-Hydroxy Carbonyl …

B Vermeeren, S Van Praet, A De Ridder… - ACS Sustainable …, 2024 - ACS Publications
Catalytic reductive amination of carbohydrate-derived α-hydroxy carbonyl oxygenates offers
an elegant approach to access both aliphatic alkanolamines and alkyl polyamines via the …

Design strategy and application of deep eutectic solvents for green synthesis of nanomaterials

NN Nam, HDK Do, KTL Trinh, NY Lee - Nanomaterials, 2023 - mdpi.com
The first report of deep eutectic solvents (DESs) was released in 2003 and was identified as
a new member of ionic liquid (IL), involving innovative chemical and physical characteristics …

Reductive amination of phenol over Pd-based catalysts: elucidating the role of the support and metal nanoparticle size

M Ortega, D Gómez, R Manrique, G Reyes… - Reaction Chemistry & …, 2023 - pubs.rsc.org
The heterogeneously catalyzed reductive amination of phenolics from lignin is considered
an attractive sustainable route for the synthesis of primary or high-order aromatic and …

Density Functional Theory Study on the Selective Reductive Amination of Aldehydes and Ketones over Their Reductions to Alcohols Using Sodium …

SJ Oliphant, RH Morris - ACS omega, 2022 - ACS Publications
Reductive amination is one of the most important methods to synthesize amines, having a
wide application in the pharmaceutical, fine chemicals, and materials industries. In general …

One-Pot Synthesis of Fatty Amines: Rh-Catalyzed Hydroaminomethylation of 1-Decene in an Aqueous Microemulsion System—Influence of Reaction Conditions on …

A Weber, L Porthun, R Schomäcker - Catalysts, 2022 - mdpi.com
The hydroaminomethylation of the long-chain olefin 1-decene and diethylamine with a
homogeneous Rh (acac)(cod)/SulfoXantphos catalyst complex as a one-pot synthesis was …

[HTML][HTML] Iterative real-time optimization of a reductive amination process in a thermomorphic multiphase system

ARG Mukkula, TB Riemer, A Kühl, D Vogt… - Chemical Engineering …, 2024 - Elsevier
In this paper, we discuss the optimization of the operation of a reductive amination (RA)
reaction process in a miniplant without an accurate process model using iterative real-time …

[HTML][HTML] Mechanistic kinetic modeling of the rhodium-catalyzed tandem hydroaminomethylation of 1-decene in a thermomorphic solvent system

W Kortuz, S Kirschtowski, A Seidel-Morgenstern… - Catalysis …, 2023 - Elsevier
For a more resource-efficient production of amines the homogeneously catalyzed tandem
hydroaminomethylation reaction is of large relevance. The kinetics of the sulfoxantphos …

Harnessing dipolar microenvironment engineering of PTSA for alkenylation of indole in butyl acetate

Z Wang, M Li, Y Gu - Green Chemistry, 2024 - pubs.rsc.org
The thiophene sulfone-functionalized hyper-crosslinked polymer (HCP) was prepared,
characterized, and used as an additive to regulate the catalytic activity of p-toluenesulfonic …