This article surveys the empirical information which originated both by laboratory
experiments and by computational simulations, and expands previous understanding of the …

The pillars of contemporary theoretical physics are classical mechanics, Maxwell
electromagnetism, relativity, quantum mechanics, and Boltzmann–Gibbs (BG) statistical …

Pyruvic acid is an atmospherically abundant α-keto-acid that degrades efficiently from the
troposphere via gas-phase photolysis. To explore conditions relevant to the environment, 2 …

The ultraviolet (UV) photodissociation of pyruvic acid through the absorption of solar actinic
flux generates methylhydroxycarbene (MHC) in the atmosphere. It is recognized that …

The recognition of the solvent effect on the enol–enol tautomerism in curcumin can guide the
rationalization of systems of chemical and biological interest. Although the phenomenon is …

The Arrhenius law has been used successfully to describe the temperature dependence for
a considerable number of rate processes in many areas of molecular science. In order to …

The formation of (HF) n aggregates with n= 2, 3, 4, 5 and 6 and concerted proton transfer
processes in these aggregates were systematically analyzed. It was verified that, by a …

Modern experimental and theoretical advances in chemical kinetics are documenting an
ample spectrum of phenomena on reactions occurring under conditions relevant for …

Devido sua composição estrutural, os carbenos são espécies altamente reativas. Com isso,
são frequentemente observados em reações químicas na forma de intermediários reativos …

A possibilidade de investigação de reações em condições adversas tem revelado
propriedades exóticas de muitas reações, a priori, bem estabelecidas em química. Uma …