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On the importance of pnictogen and chalcogen bonding interactions in supramolecular catalysis
A Frontera, A Bauza - International Journal of Molecular Sciences, 2021 - mdpi.com
In this review, several examples of the application of pnictogen (Pn)(group 15) and
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
Participation of S and Se in hydrogen and chalcogen bonds
S Scheiner - CrystEngComm, 2021 - pubs.rsc.org
This article reviews the history and the current state of knowledge concerning the ability of
the heavy chalcogen atoms S and Se, and to some extent Te, to participate in a H-bond as …
the heavy chalcogen atoms S and Se, and to some extent Te, to participate in a H-bond as …
A Bidentate Antimony Pnictogen Bonding Host System
JL Beckmann, J Krieft, YV Vishnevskiy… - Angewandte Chemie …, 2023 - Wiley Online Library
A bidentate pnictogen bonding host‐system based on 1, 8‐diethynylanthracene was
synthesized by a selective tin‐antimony exchange reaction and investigated regarding its …
synthesized by a selective tin‐antimony exchange reaction and investigated regarding its …
Pnictogen‐Bonding Catalysts, Compared to Tetrel‐Bonding Catalysts: More Than Just Weak Lewis Acids
H Chen, A Frontera… - Helvetica Chimica …, 2022 - Wiley Online Library
A hyperresponsive tool to assess supramolecular catalysis, the cyclization of di‐epoxides
into cyclic ethers is used to elucidate the difference between pnictogen‐bonding and Lewis …
into cyclic ethers is used to elucidate the difference between pnictogen‐bonding and Lewis …
Interaction nature and computational methods for halogen bonding: a perspective
Halogen bonds are noncovalent interactions that have been widely used in many fields,
including drug design, crystal engineering, and material sciences. A clear understanding of …
including drug design, crystal engineering, and material sciences. A clear understanding of …
Poly-pnictogen bonding: trap** halide ions by a tetradentate antimony (iii) Lewis acid
JL Beckmann, J Krieft, YV Vishnevskiy, B Neumann… - Chemical …, 2023 - pubs.rsc.org
A highly halide affine, tetradentate pnictogen-bonding host-system based on the syn-
photodimer of 1, 8-diethynylanthracene was synthesized by a selective tin-antimony …
photodimer of 1, 8-diethynylanthracene was synthesized by a selective tin-antimony …
Catalysis of the Nitroso–Diels–Alder cycloaddition reaction between CH3N= O and cis-1, 3-butadiene by pnictogen bonding, a theoretical study
F Yaghoobi, S Salehzadeh - Journal of Molecular Graphics and Modelling, 2023 - Elsevier
Density functional theory calculations at the M06-2X/aug-cc-pVTZ level of theory have been
used to examine the Nitroso–Diels–Alder (N–D–A) cycloaddition reaction between the CH 3 …
used to examine the Nitroso–Diels–Alder (N–D–A) cycloaddition reaction between the CH 3 …
Chalcogen and pnictogen bonds: insights and relevance.
Hydrogen bonding (HB) and halogen bonding (XB) interactions are now well established as
important noncovalent forces across different research areas. Chalcogen bonding (ChB) …
important noncovalent forces across different research areas. Chalcogen bonding (ChB) …
[HTML][HTML] Evolution of design approaches in asymmetric organocatalysis over the last decade
This perspective intends to cover the vast field of asymmetric organocatalysis and its
evolution during the last ten years. This work has evaluated the corresponding timeline of …
evolution during the last ten years. This work has evaluated the corresponding timeline of …
Relative strengths of a pnicogen and a tetrel bond and their mutual effects upon one another
S Scheiner - The Journal of Physical Chemistry A, 2021 - ACS Publications
The ability of the T and Z atoms of TR3ZR2 to engage in a noncovalent interaction with NH3
is assessed by DFT calculations, where the T atom refers to C, Si, and Ge; Z= As, Sb, and P; …
is assessed by DFT calculations, where the T atom refers to C, Si, and Ge; Z= As, Sb, and P; …