Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

A historical overview of the activation and porosity of metal–organic frameworks

X Zhang, Z Chen, X Liu, SL Hanna, X Wang… - Chemical Society …, 2020 - pubs.rsc.org
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …

[HTML][HTML] Upscaled production of an ultramicroporous anion-exchange membrane enables long-term operation in electrochemical energy devices

W Song, K Peng, W Xu, X Liu, H Zhang, X Liang… - Nature …, 2023 - nature.com
The lack of high-performance and substantial supply of anion-exchange membranes is a
major obstacle to future deployment of relevant electrochemical energy devices. Here, we …

Highly flexible and superhydrophobic MOF nanosheet membrane for ultrafast alcohol-water separation

LH Xu, SH Li, H Mao, Y Li, AS Zhang, S Wang, WM Liu… - Science, 2022 - science.org
High-performance pervaporation membranes have potential in industrial separation
applications, but overcoming the permeability-selectivity trade-off is a challenge. We report a …

Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries

H Kwak, JS Kim, D Han, JS Kim, J Park, G Kwon… - Nature …, 2023 - nature.com
Designing highly conductive and (electro) chemical stable inorganic solid electrolytes using
cost-effective materials is crucial for develo** all-solid-state batteries. Here, we report …

New Oxyhalide Solid Electrolytes with High Lithium Ionic Conductivity >10 mS cm−1 for All‐Solid‐State Batteries

Y Tanaka, K Ueno, K Mizuno… - Angewandte Chemie …, 2023 - Wiley Online Library
All‐solid‐state batteries (ASSBs) with inorganic solid electrolytes (SEs) have attracted
significant interest as next‐generation energy storage. Halides such as Li3YCl6 are …

A multi-modal pre-training transformer for universal transfer learning in metal–organic frameworks

Y Kang, H Park, B Smit, J Kim - Nature Machine Intelligence, 2023 - nature.com
Metal–organic frameworks (MOFs) are a class of crystalline porous materials that exhibit a
vast chemical space owing to their tunable molecular building blocks with diverse …

Computational discovery of transition-metal complexes: from high-throughput screening to machine learning

A Nandy, C Duan, MG Taylor, F Liu, AH Steeves… - Chemical …, 2021 - ACS Publications
Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

A molecular sieve with ultrafast adsorption kinetics for propylene separation

J Cui, Z Zhang, L Yang, J Hu, A **, Z Yang, Y Zhao… - Science, 2024 - science.org
The design of molecular sieves is vital for gas separation, but it suffers from a long-standing
issue of slow adsorption kinetics due to the intrinsic contradiction between molecular sieving …

Sha** the water-harvesting behavior of metal–organic frameworks aided by fine-tuned GPT models

Z Zheng, AH Alawadhi, S Chheda… - Journal of the …, 2023 - ACS Publications
We construct a data set of metal–organic framework (MOF) linkers and employ a fine-tuned
GPT assistant to propose MOF linker designs by mutating and modifying the existing linker …