High-voltage liquid electrolytes for Li batteries: progress and perspectives

X Fan, C Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
Since the advent of the Li ion batteries (LIBs), the energy density has been tripled, mainly
attributed to the increase of the electrode capacities. Now, the capacity of transition metal …

Oxygen loss in layered oxide cathodes for Li-ion batteries: mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Trapped O2 and the origin of voltage fade in layered Li-rich cathodes

JJ Marie, RA House, GJ Rees, AW Robertson… - Nature Materials, 2024 - nature.com
Oxygen redox cathodes, such as Li1. 2Ni0. 13Co0. 13Mn0. 54O2, deliver higher energy
densities than those based on transition metal redox alone. However, they commonly exhibit …

Decoupling the roles of Ni and Co in anionic redox activity of Li-rich NMC cathodes

B Li, Z Zhuo, L Zhang, A Iadecola, X Gao, J Guo… - Nature Materials, 2023 - nature.com
Abstract Li [Li x Ni y Mn z Co1− x− y− z] O2 (lithium-rich NMCs) are benchmark cathode
materials receiving considerable attention due to the abnormally high capacities resulting …

Improving the oxygen redox reversibility of Li-rich battery cathode materials via Coulombic repulsive interactions strategy

Q Li, D Ning, D Wong, K An, Y Tang, D Zhou… - Nature …, 2022 - nature.com
The oxygen redox reaction in lithium-rich layered oxide battery cathode materials generates
extra capacity at high cell voltages (ie,> 4.5 V). However, the irreversible oxygen release …

Thermodynamically Stable Dual‐Modified LiF&FeF3 layer Empowering Ni‐Rich Cathodes with Superior Cyclabilities

Y Chu, Y Mu, L Zou, Y Hu, J Cheng, B Wu… - Advanced …, 2023 - Wiley Online Library
Pushing the limit of cutoff potentials allows nickel‐rich layered oxides to provide greater
energy density and specific capacity whereas reducing thermodynamic and kinetic stability …

Understanding Lattice Oxygen Redox Behavior in Lithium‐Rich Manganese‐Based Layered Oxides for Lithium‐Ion and Lithium‐Metal Batteries from Reaction …

C Shen, L Hu, Q Duan, X Liu, S Huang… - Advanced Energy …, 2023 - Wiley Online Library
Lithium‐rich manganese‐based layered oxides (LMLOs) are considered to be one type of
the most promising materials for next‐generation cathodes of lithium batteries due to their …

Advanced cobalt-free cathode materials for sodium-ion batteries

S Chu, S Guo, H Zhou - Chemical Society Reviews, 2021 - pubs.rsc.org
Attempts to utilize lithium-ion batteries (LIBs) in large-scale electrochemical energy storage
systems have achieved initial success, and solid-state LIBs using metallic lithium as the …

A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

J Langdon, A Manthiram - Energy Storage Materials, 2021 - Elsevier
As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-
vehicle and grid-storage markets, the need for higher energy density and longer cycle life …

Van der Waals phase transition investigation toward high-voltage layered cathodes

A Gao, S Shen, T Shang, Y Shi, H Zhang, W Lin… - Science …, 2024 - science.org
High-voltage phase transition constitutes the major barrier to accessing high energy density
in layered cathodes. However, questions remain regarding the origin of phase transition …