Copper active sites in biology
On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …
The isotope geochemistry of zinc and copper
Copper, a native metal found in ores, is the principal metal in bronze and brass. It is a
reddish metal with a density of 8920 kg m− 3. All of copper's compounds tend to be brightly …
reddish metal with a density of 8920 kg m− 3. All of copper's compounds tend to be brightly …
Continuous electroproduction of formate via CO2 reduction on local symmetry-broken single-atom catalysts
Atomic-level coordination engineering is an efficient strategy for tuning the catalytic
performance of single-atom catalysts (SACs). However, their rational design has so far been …
performance of single-atom catalysts (SACs). However, their rational design has so far been …
Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper
Electrocatalytic reduction of CO2 into multicarbon (C2+) products is a highly attractive route
for CO2 utilization; however, the yield of C2+ products remains low because of the limited …
for CO2 utilization; however, the yield of C2+ products remains low because of the limited …
Photocatalytic C–C coupling from carbon dioxide reduction on copper oxide with mixed-valence copper (I)/copper (II)
W Wang, C Deng, S **e, Y Li, W Zhang… - Journal of the …, 2021 - ACS Publications
To realize the evolution of C2+ hydrocarbons like C2H4 from CO2 reduction in
photocatalytic systems remains a great challenge, owing to the gap between the relatively …
photocatalytic systems remains a great challenge, owing to the gap between the relatively …
Dynamic multinuclear sites formed by mobilized copper ions in NOx selective catalytic reduction
Copper ions exchanged into zeolites are active for the selective catalytic reduction (SCR) of
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
2D Copper Tetrahydroxyquinone Conductive Metal–Organic Framework for Selective CO2 Electrocatalysis at Low Overpotentials
Metal–organic frameworks (MOFs) are promising materials for electrocatalysis; however,
lack of electrical conductivity in the majority of existing MOFs limits their effective utilization in …
lack of electrical conductivity in the majority of existing MOFs limits their effective utilization in …
A supramolecular metalloenzyme possessing robust oxidase-mimetic catalytic function
S Xu, H Wu, S Liu, P Du, H Wang, H Yang, W Xu… - Nature …, 2023 - nature.com
Enzymes fold into unique three-dimensional structures to distribute their reactive amino acid
residues, but environmental changes can disrupt their essential folding and lead to …
residues, but environmental changes can disrupt their essential folding and lead to …
Bioinspired metal–organic framework catalysts for selective methane oxidation to methanol
Particulate methane monooxygenase (pMMO) is an enzyme that oxidizes methane to
methanol with high activity and selectivity. Limited success has been achieved in …
methanol with high activity and selectivity. Limited success has been achieved in …
Construction and identification of highly active single-atom Fe1-NC catalytic site for electrocatalytic nitrate reduction
Atomically dispersed metal-NC sites are highly active and selective for nitrate reduction
reaction (NO 3 RR), while identifying their coordination and geometry structures remains …
reaction (NO 3 RR), while identifying their coordination and geometry structures remains …