The use of molecules bridged between two electrodes as a stable rectifier is an important
goal in molecular electronics. Until recently, however, and despite extensive experimental …

We review charge transport across molecular monolayers, which is central to molecular
electronics (MolEl), using large-area junctions (NmJ). We strive to provide a wide conceptual …

Highly-efficient molecular photoswitching occurs ex-situ but not to-date inside electronic
devices due to quenching of excited states by background interactions. Here we achieve …

Molecular diodes operating in the tunnelling regime are intrinsically limited to a maximum
rectification ratio R of∼ 103. To enhance this rectification ratio to values comparable to …

Molecular electronics is driven by the dream of expanding Moore's law to the molecular level
for next‐generation electronics through incorporating individual or ensemble molecules into …

Unimolecular electronics (UME) narrowly defined (sensu stricto), 1 or molecular-scale
electronics, 2 is the study of electrical processes measured or controlled on a molecular …

To understand the electrical and charge transport phenomena in either single or large‐scale
molecular junctions, direct current (DC) measurements are mainly utilized. The current …

A challenge in molecular electronics is to control the strength of the molecule–electrode
coupling to optimize device performance. Here we show that non-covalent contacts between …

Analysis of rates of tunneling across self-assembled monolayers (SAMs) of n-
alkanethiolates SC n (with n= number of carbon atoms) incorporated in junctions having …

An ultimate goal of molecular electronics, which seeks to incorporate molecular components
into electronic circuit units, is to generate functional molecular electronic devices using …