Regioselective substitution of BINOL

L Pu - Chemical Reviews, 2024‏ - ACS Publications
1, 1′-Bi-2-naphthol (BINOL) has been extensively used as the chirality source in the fields
of molecular recognition, asymmetric synthesis, and materials science. The direct …

Enantioselective dialkylzinc-mediated alkynylation, arylation and alkenylation of carbonyl groups

T Bauer - Coordination Chemistry Reviews, 2015‏ - Elsevier
Enantiopure diarylmethanols, propargylic and allylic alcohols are important building blocks
for the synthesis of a plethora of natural products and pharmaceutically relevant compounds …

Enantioselective alkynylation of aldehydes with 1-haloalkynes catalyzed by tethered bis (8-quinolinato) chromium complex

DL Usanov, H Yamamoto - Journal of the American Chemical …, 2011‏ - ACS Publications
The first example of Cr-catalyzed asymmetric alkynylation of aldehydes with 1-iodo-and 1-
bromoalkynes was developed. The use of tethered bis (8-quinolinato) chromium catalyst (3 …

Enantioselective titanium-promoted 1, 2-additions of carbon nucleophiles to carbonyl compounds

H Pellissier - Tetrahedron, 2015‏ - Elsevier
The goal of this review is to collect the major developments in enantioselective titanium-
promoted 1, 2-alkylation, 1, 2-arylation, 1, 2-alkynylation, 1, 2-allylation and 1, 2-vinylation …

A fluorescence sensor based on chiral polymer for highly enantioselective recognition of phenylalaninol

J Meng, G Wei, X Huang, Y Dong, Y Cheng, C Zhu - Polymer, 2011‏ - Elsevier
The chiral polymer P-1 incorporating (S)-2, 2′-binaphthol (BINOL) and (S)-2, 2′-
binaphthyldiamine (BINAM) moieties in the main chain of the polymer backbone was …

A coumarin-based chiral fluorescence sensor for the highly enantioselective recognition of phenylalaninol

J Jiao, X Liu, X Mao, J Li, Y Cheng, C Zhu - New Journal of Chemistry, 2013‏ - pubs.rsc.org
A chiral host L1 incorporating (S)-BINOL and substituted coumarin moieties was synthesized
via a nucleophilic addition–elimination reaction, and ligand L2 could be obtained by the …

Recent developments in enantioselective titanium-catalyzed transformations

H Pellissier - Coordination Chemistry Reviews, 2022‏ - Elsevier
This review collects the recent developments in the field of enantioselective titanium-
catalyzed transformations published since the beginning of 2015, illustrating the power of …

Synthesis and properties of chiral helical polymers based on optically active polybinaphthyls

X Huang, Y Xu, Q Miao, L Zong, H Hu, Y Cheng - Polymer, 2009‏ - Elsevier
The chiral polymer P-1 was synthesized by the polymerization of (R)-6, 6′-dibutyl-3, 3′-
diiodo-2, 2′-bisoctoxy-1, 1′-binaphthyl (RM-1) with 5, 5′-divinyl-2, 2′-bipyridine (M-1) …

A polymer based fluorescent sensor for Zn2+ detection and its application for constructing logic gates

Y Dong, Y Wu, X Jiang, X Huang, Y Cheng, C Zhu - Polymer, 2011‏ - Elsevier
A polymer-based fluorescent sensor was synthesized by polymerization of (S)-6, 6′-dibutyl-
3, 3′-(di-5-salicylde-ethynyl)-2, 2′-binaphthol (M-1) with (R, R)-1, 2-diaminocyclohexane …

Synthesis and Fluorescent Properties of a Chiral Conjugated Polymer Based on (S)-2,2′-Binaphtho-20-crown-6

H Huang, Q Miao, Y Kang, X Huang… - Bulletin of the …, 2008‏ - academic.oup.com
Linear conjugated polymer was obtained by the polymerization of 2, 3-dibutoxy-1, 4-
diethynylnaphthalene (M-1) and (S)-5, 5′-dibromo-6, 6′-dibutyl-2, 2′-binaphtho-20 …