The peculiar effect of water on ionic liquids and deep eutectic solvents

C Ma, A Laaksonen, C Liu, X Lu, X Ji - Chemical Society Reviews, 2018 - pubs.rsc.org
Ionic liquids (ILs) and deep eutectic solvents (DESs) have been suggested as eco-friendly
alternatives to organic solvents. A trace amount of water is often unavoidable as impurity …

Multiscale studies on ionic liquids

K Dong, X Liu, H Dong, X Zhang, S Zhang - Chemical reviews, 2017 - ACS Publications
Ionic liquids (ILs) offer a wide range of promising applications because of their much
enhanced properties. However, further development of such materials depends on the …

NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids

J Zhang, H Zhang, J Wu, J Zhang, J He… - Physical Chemistry …, 2010 - pubs.rsc.org
The dissolution mechanism of cellulose in ionic liquids has been investigated by using
cellobiose and 1-ethyl-3-methylimidazolium acetate (EmimAc) as a model system under …

Direct dissolution of cellulose: background, means and applications

C Olsson, G Westman - Cellulose-fundamental aspects, 2013 - books.google.com
Being the main structural component in plants, cellulose is by far the most abundant organic
polymer on earth. The highest quantity of cellulose is found in the secondary walls of higher …

Polarizability versus mobility: atomistic force field for ionic liquids

V Chaban - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
Based on classical molecular dynamics simulations, we discuss the impact of Coulombic
interactions on a comprehensive set of properties of room temperature ionic liquids (RTILs) …

Tailored media for homogeneous cellulose chemistry: ionic liquid/co‐solvent mixtures

M Gericke, T Liebert, OAE Seoud… - Macromolecular …, 2011 - Wiley Online Library
Co‐solvents can minimize two of the major problems associated with the use of ionic liquids
(ILs) as solvents for homogeneous derivatization of cellulose: high viscosity and limited …

Rheological properties of cellulose/ionic liquid/dimethylsulfoxide (DMSO) solutions

Y Lv, J Wu, J Zhang, Y Niu, CY Liu, J He, J Zhang - Polymer, 2012 - Elsevier
Rheological properties of cellulose dissolved in two ionic liquids (ILs), 1-allyl-3-
methylimidazolium chloride (AmimCl) and 1-butyl-3-methylimidazolium chloride (BmimCl) …

Dissecting force interactions in cellulose deconstruction reveals the required solvent versatility for overcoming biomass recalcitrance

HM Cho, AS Gross, JW Chu - Journal of the American Chemical …, 2011 - ACS Publications
Pretreatment for deconstructing the multifaceted interaction network in crystalline cellulose is
a limiting step in making fuels from lignocellulosic biomass. Not soluble in water and most …

Computational studies of room temperature ionic liquid–water mixtures

BL Bhargava, Y Yasaka, ML Klein - Chemical Communications, 2011 - pubs.rsc.org
Room temperature ionic liquids (IL) have been used in numerous applications in chemistry.
Addition of water alters many of their properties making it possible to custom design solvents …

Association of ionic liquids in solution: a combined dielectric and conductivity study of [bmim][Cl] in water and in acetonitrile

M Bešter-Rogač, A Stoppa, J Hunger… - Physical Chemistry …, 2011 - pubs.rsc.org
Ion association of the ionic liquid [bmim][Cl] in acetonitrile and in water was studied by
dielectric spectroscopy for salt concentrations c≤ 1.3 M at 298.15 K and by measurement of …