This study delves into the magnetic response of core electrons and their influence on the
global magnetic response of planar and three-dimensional systems containing heavy …

Herein we report a square-like D4h H© K4H4− anion with one planar tetracoordinate
hydrogen (ptH) center, which is the global minimum (GM) structure and possesses good …

Despite the long list of planar tetracoordinate atoms, hydrogen is elusive. This is especially
due to the inherent ability of hydrogen to form multicenter bonds with other centers. Herein …

The recent report of planar tetracoordinate hydrogen (ptH) in In4H+ is very intriguing in
planar hypercoordinate chemistry. Our high-level CCSD (T) calculations revealed that the …

Among the known planar pentacoordinate atoms, chlorine is missing due to its large radius
and high electronegativity. Herein, we report the first star-like superhalogen anion D 5 h Cl© …

Planar tetracoordinate fluorine (ptF) species are very exotic and scarce due to high
electronegativity of fluorine. Herein we report the ternary square ptF cluster, D 4 h FK4H4 …

Planar hypercoordinate motifs represent an intriguing frontier in chemistry, challenging
traditional bonding norms. As electronegativity of the central atom increases, achieving …

A D5h hydrocopper H© Cu5H5− star with planar pentacoordinate hydrogen (ppH) was
designed. This structure is the global minimum, exhibiting dynamic stability. Its planar …

Recently, Guha and co-workers (Sarmah, K.; Kalita, A.; Purkayastha, S.; Guha, AK Pushing
The Extreme of Multicentre Bonding: Planar Pentacoordinate Hydride. Angew. Chem. Int …

Despite the inherent stability-enhancing benefits of dπ–pπ conjugation-induced aromaticity,
metallaaromatic catalysts remain underutilized in this context, despite their reactivity with …