Cycloheptatrienyl, alkyl and aryl PCP-pincer complexes: Ligand backbone effects and metal reactivity

W Leis, HA Mayer, WC Kaska - Coordination Chemistry Reviews, 2008 - Elsevier
Pincer complexes have developed into a class of compounds with a tremendous breadth of
applications in organometallic chemistry and catalysis. In this article we have selected a few …

Recent advances on the chemistry of POCOP–nickel pincer compounds

M Asay, D Morales-Morales - The Privileged Pincer-Metal Platform …, 2016 - Springer
A description of the vertiginous development of the chemistry of POCOP–Ni complexes and
their applications is described. Recent advances include the discovery and initially …

Highly active iridium catalysts for alkane dehydrogenation. Synthesis and properties of iridium bis (phosphine) pincer complexes based on ferrocene and ruthenocene

SA Kuklin, AM Sheloumov, FM Dolgushin… - …, 2006 - ACS Publications
Novel bis (phosphine) pincer complexes of iridium based on ferrocene and ruthenocene
have been synthesized. The reaction of 1, 3-bis ((di-tert-butylphosphino) methyl) …

Bimetallic complexes that merge metallocene and pincer-metal building blocks: synthesis, stereochemistry and catalytic reactivity

H Valdés, JM Germán-Acacio, G Van Koten… - Dalton …, 2022 - pubs.rsc.org
This perspective is to illustrate the synthesis and applications of bimetallic complexes by
merging a metallocene and a (cyclopentadienyl/aryl) pincer metal complex. Four possible …

A halogen bonding 1, 3‐disubstituted ferrocene receptor for recognition and redox sensing of azide

JYC Lim, PD Beer - European Journal of Inorganic Chemistry, 2017 - Wiley Online Library
A neutral redox‐active acyclic halogen bonding (XB) receptor with a ferrocene core
functionalised at the 1, 3‐positions of a cyclopentadienyl ring with iodotriazole motifs is …

Dehydrogenation of alcohols by bis (phosphinite) benzene based and bis (phosphine) ruthenocene based iridium pincer complexes

AV Polukeev, PV Petrovskii, AS Peregudov… - …, 2013 - ACS Publications
Dehydrogenation of alcohols by three iridium pincer complexes, IrH (Cl)[2, 6-(t Bu2PO)
2C6H3](1),{IrH (acetone)[2, 6-(t Bu2PO) 2C6H3]}{BF4}(2), and IrH (Cl)[{2, 5-(t Bu2PCH2) …

Ferrocene-based pincer complexes of palladium: Synthesis, structures, and spectroscopic and electrochemical properties

AA Koridze, SA Kuklin, AM Sheloumov… - …, 2004 - ACS Publications
Palladium P, C, P pincer complexes based on ferrocene were synthesized for the first time.
The reaction of the 1, 3-bis ((dialkylphosphino) methyl) ferrocenes {1, 3-(R2PCH2) 2C5H3} …

Oxidation-promoted activation of a ferrocene C–H bond by a rhodium complex

A Labande, N Debono, A Sournia-Saquet… - Dalton …, 2013 - pubs.rsc.org
The oxidation of a rhodium (I) complex containing a ferrocene-based heterodifunctional
phosphine N-heterocyclic carbene (NHC) ligand produces a stable, planar chiral rhodium …

Coordination of 12-electron organometallic fragments to the arene ring of nonsymmetric group 10 POCOP pincer complexes

NA Espinosa-Jalapa, S Hernandez-Ortega… - …, 2013 - ACS Publications
A series of heterobimetallic complexes have been prepared in good yields by η6
coordination of [Cp* Ru]+,[CpRu]+,[CpFe]+, and [Cr (CO) 3] fragments to the aromatic ring of …

Bimetallic η61 SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity

S Bonnet, M Lutz, AL Spek, G van Koten… - …, 2010 - ACS Publications
The synthesis of η6, η1 SCS-and PCP-pincer ruthenium palladium complexes [3]+−[6]+ by
direct η6-coordination of [Ru (C5R5)]+(R= H or Me) to the arene ring of η1-palladated ECE …