Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Telechelic polymers by living and controlled/living polymerization methods

MA Tasdelen, MU Kahveci, Y Yagci - Progress in Polymer Science, 2011 - Elsevier
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …

Chemically recyclable linear and branched polyethylenes synthesized from stoichiometrically self-balanced telechelic polyethylenes

YJ Jang, S Nguyen, MA Hillmyer - Journal of the American …, 2024 - ACS Publications
High-density polyethylene (HDPE) is a widely used commercial plastic due to its excellent
mechanical properties, chemical resistance, and water vapor barrier properties. However …

PLA synthesis. From the monomer to the polymer

K Masutani, Y Kimura - 2014 - books.rsc.org
It is recorded that Théophile-Jules Pelouze first synthesized poly (lactic acid)(PLA) by
polycondensation of lactic acid in 1845. 1 In 1932, Wallace Hume Carothers et al …

Development of well-defined olefin block (co) polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization

Y Wang, J Lai, Q Gou, R Gao, G Zheng, R Zhang… - Coordination Chemistry …, 2025 - Elsevier
As the saturation rate of the bulk polyolefin market accelerates, the development of high
value-added polyolefins becomes increasingly urgent. Particular attention is directed …

Unexpected consequences of block polydispersity on the self-assembly of ABA triblock copolymers

JM Widin, AK Schmitt, AL Schmitt, K Im… - Journal of the …, 2012 - ACS Publications
Controlled/“living” polymerizations and tandem polymerization methodologies offer enticing
opportunities to enchain a wide variety of monomers into new, functional block copolymer …

Ring-opening metathesis polymerization of 8-membered cyclic olefins

H Martinez, N Ren, ME Matta, MA Hillmyer - Polymer Chemistry, 2014 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such
as the parent molecules cis-cyclooctene (COE) and cis, cis-1, 5-cyclooctadiene (COD) …

Supersoft Norbornene‐Based Thermoplastic Elastomers with High Strength and Upper Service Temperature

HL Cater, MJ Allen, MI Linnell, AK Rylski… - Advanced …, 2024 - Wiley Online Library
With over 6 million tons produced annually, thermoplastic elastomers (TPEs) have become
ubiquitous in modern society, due to their unique combination of elasticity, toughness, and …

A Virtual Issue of Macromolecules: “Polymers from Renewable Resources”

GW Coates, MA Hillmyer - Macromolecules, 2009 - ACS Publications
It is our pleasure to announce the second “virtual issue” for Macromolecules. A virtual issue
collects a set of recently published Macromolecules papers in a Web-only edition of the …

Synthesis of poly (lactide) s with modified thermal and mechanical properties

JM Becker, RJ Pounder, AP Dove - Macromolecular rapid …, 2010 - Wiley Online Library
The use of poly (lactide)‐based materials is, in part, limited by their physical and mechanical
properties. This article reviews the methods that have been employed to enable …