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A review on photothermal conversion of solar energy with nanomaterials and nanostructures: from fundamentals to applications
Solar energy is a green, sustainable, and de facto inexhaustible energy source for mankind.
The conversion of solar energy into other forms of energy has attracted extensive research …
The conversion of solar energy into other forms of energy has attracted extensive research …
Photo-and electro-chemical strategies for the activations of strong chemical bonds
X Tian, Y Liu, S Yakubov, J Schütte, S Chiba… - Chemical Society …, 2024 - pubs.rsc.org
The employment of light and/or electricity–alternatively to conventional thermal energy–
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …
Photocatalytic hydrofluoroalkylation of alkenes with carboxylic acids
Incorporation of fluoroalkyl motifs in pharmaceuticals can enhance the therapeutic profiles of
the parent molecules. The hydrofluoroalkylation of alkenes has emerged as a promising …
the parent molecules. The hydrofluoroalkylation of alkenes has emerged as a promising …
Recent advances in reactions involving carbon dioxide radical anion
W **ao, J Zhang, J Wu - ACS Catalysis, 2023 - ACS Publications
Carbon dioxide radical anion (CO2•–) is a highly reactive nucleophilic radical species that
has recently emerged in organic chemistry as a strong single electron donor (reductant) and …
has recently emerged in organic chemistry as a strong single electron donor (reductant) and …
Dicarboxylation of Alkenes with CO2 and Formate via Photoredox Catalysis
P Xu, S Wang, H Xu, YQ Liu, RB Li, WW Liu… - ACS …, 2023 - ACS Publications
Herein, a photocatalytic strategy for the synthesis of succinic acids by alkene dicarboxylation
with carbon dioxide (CO2) and formate salt as synergistic carbon sources is described. The …
with carbon dioxide (CO2) and formate salt as synergistic carbon sources is described. The …
Photoinduced copper-catalyzed C–N coupling with trifluoromethylated arenes
J Huang, Q Gao, T Zhong, S Chen, W Lin… - Nature …, 2023 - nature.com
Selective defluorinative functionalization of trifluoromethyl group (–CF3) is an attractive
synthetic route to the pharmaceutically privileged fluorine-containing moiety. Herein, we …
synthetic route to the pharmaceutically privileged fluorine-containing moiety. Herein, we …
Arenethiolate as a dual function catalyst for photocatalytic defluoroalkylation and hydrodefluorination of trifluoromethyls
C Liu, K Li, R Shang - ACS Catalysis, 2022 - ACS Publications
Thiol is known to act as a hydrogen atom transfer catalyst working in synergy with a
photocatalyst in photoredox catalysis, but we report herein that an arene thiolate with an …
photocatalyst in photoredox catalysis, but we report herein that an arene thiolate with an …
C− F bond activation enables synthesis of aryl difluoromethyl bicyclopentanes as benzophenone-type bioisosteres
Bioisosteric design has become an essential approach in the development of drug
molecules. Recent advancements in synthetic methodologies have enabled the rapid …
molecules. Recent advancements in synthetic methodologies have enabled the rapid …
Recent discovery, development, and synthetic applications of formic acid salts in photochemistry
The advancement of sustainable photoredox catalysis in synthetic organic chemistry has
evolved immensely because of the development of versatile and cost‐effective reagents. In …
evolved immensely because of the development of versatile and cost‐effective reagents. In …
Photoredox/HAT-Catalyzed Dearomative Nucleophilic Addition of the CO2 Radical Anion to (Hetero)Aromatics
SR Mangaonkar, H Hayashi, H Takano, W Kanna… - ACS …, 2023 - ACS Publications
The radical anion of CO2 (CO2•–) is a strongly nucleophilic radical species with rapidly
emerging applications in contemporary organic chemistry. This radical species exhibits high …
emerging applications in contemporary organic chemistry. This radical species exhibits high …