New advances in covalent network polymers via dynamic covalent chemistry

Z Lei, H Chen, S Huang, LJ Wayment, Q Xu… - Chemical …, 2024 - ACS Publications
Covalent network polymers, as materials composed of atoms interconnected by covalent
bonds in a continuous network, are known for their thermal and chemical stability. Over the …

Covalent organic frameworks enable sustainable solar to hydrogen peroxide

D Tan, R Zhuang, R Chen, M Ban… - Advanced Functional …, 2024 - Wiley Online Library
As a chemical product with rapidly expanding demand in the field of modern energy and
environmental applications, hydrogen peroxide (H2O2) has garnered widespread attention …

In Situ Synthesis of Chemically Bonded 2D/2D Covalent Organic Frameworks/O‐Vacancy WO3 Z‐Scheme Heterostructure for Photocatalytic Overall Water Splitting

R Shen, G Liang, L Hao, P Zhang, X Li - Advanced Materials, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) have shown great promise for photocatalytic hydrogen
evolution via water splitting. However, the four‐electron oxidation of water remains elusive …

Exceptionally high charge mobility in phthalocyanine-based poly (benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

M Wang, S Fu, P Petkov, Y Fu, Z Zhang, Y Liu, J Ma… - Nature Materials, 2023 - nature.com
Two-dimensional conjugated polymers (2DCPs), composed of multiple strands of linear
conjugated polymers with extended in-plane π-conjugation, are emerging crystalline …

Covalent organic frameworks as porous pigments for photocatalytic metal-free C–H borylation

A Basak, S Karak, R Banerjee - Journal of the American Chemical …, 2023 - ACS Publications
Covalent organic frameworks (COFs) are highly promising as heterogeneous photocatalysts
due to their tunable structures and optoelectronic properties. Though COFs have been used …

Highly crystalline polyimide covalent organic framework as dual-active-center cathode for high-performance lithium-ion batteries

L Yao, C Ma, L Sun, D Zhang, Y Chen… - Journal of the …, 2022 - ACS Publications
Polyimide covalent organic framework (PI-COF) materials that can realize intrinsic redox
reactions by changing the charge state of their electroactive sites are considered as …

Efficient Adsorption of Acetylene over CO2 in Bioinspired Covalent Organic Frameworks

Z Zhang, C Kang, SB Peh, D Shi, F Yang… - Journal of the …, 2022 - ACS Publications
Rational design of covalent organic frameworks (COFs) to broaden their diversity is highly
desirable but challenging due to the limited, expensive, and complex building blocks …

Fluorenone-based covalent organic frameworks with efficient exciton dissociation and well-defined active center for remarkable photocatalytic hydrogen evolution

L Hao, R Shen, C Huang, Z Liang, N Li, P Zhang… - Applied Catalysis B …, 2023 - Elsevier
Precisely modulating both the fine structures and exciton behaviors of covalent organic
framework (COF)-based photocatalysts for efficient photocatalytic hydrogen evolution is still …

Covalent organic framework thin-film photodetectors from solution-processable porous nanospheres

S Bag, HS Sasmal, SP Chaudhary, K Dey… - Journal of the …, 2023 - ACS Publications
The synthesis of homogeneous covalent organic framework (COF) thin films on a desired
substrate with decent crystallinity, porosity, and uniform thickness has great potential for …

Postsynthetic Annulation of Three-Dimensional Covalent Organic Frameworks for Boosting CO2 Photoreduction

P Dong, X Xu, R Luo, S Yuan, J Zhou… - Journal of the American …, 2023 - ACS Publications
Three-dimensional covalent organic frameworks (3D COFs), with interconnected pores and
exposed functional groups, provide new opportunities for the design of advanced functional …