Homogeneous electrocatalysis has been well studied over the past several decades for the
conversion of small molecules to useful products for green energy applications or as …

The cyclopentadienyl (Cp) ligand is a cornerstone of modern organometallic chemistry.
Since the discovery of ferrocene, the Cp ligand and its various derivatives have become …

Catalytic π-arene activation is based on catalysts that allow for arene exchange. To date,
cyclopentadiene (Cp)-derived catalysts are the most commonly used in π-arene activation …

The rapid and efficient conversion of carbon dioxide (CO2) to carbon monoxide (CO) is an
ongoing challenge. Catalysts based on iron-porphyrin cores have emerged as excellent …

We report herein a protocol for the selective activation of C (sp 3)–H bonds based on the
interplay of two readily available organic catalysts and their successful implementation in …

Deoxygenation of phosphine oxides is of great significance to synthesis of phosphorus
ligands and relevant catalysts, as well as to the sustainability of phosphorus chemistry …

The formation of hydrides at heterogeneous copper surfaces results in dramatic structural
and reactivity changes, yet the morphologies of these materials and their respective roles in …

A general method for the light-driven intermolecular anti-Markovnikov hydroamination of
alkenes with primary sulfonamides, sulfamides, and sulfamates is presented. The reaction is …

Anion-binding interactions in nature have enabled the development of organocatalytic
transformations; however, even though ionic species act as intermediates or precursors in …

Coordination of alcohols to the single-electron reductant samarium diiodide (SmI2) results in
substantial O–H bond weakening, affording potent proton-coupled electron transfer (PCET) …