With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past
decade, NHC metal complexes have gained wide applications in the research field of …

Over the course of the past 15 years the success story of N-heterocyclic carbene (NHC)
compounds in organic, inorganic, and organometallic chemistry has been extended to …

Silica-supported metal complex catalysts have been developed and used for organic
transformations. The surface environment around the supported metal complex enhances …

Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the
system of choice for homogeneous catalysis with well-defined molecular active species due …

Palladium-catalyzed cross-coupling reactions are recognized as fundamental
transformations in chemistry.[1] The general mechanism for these reactions under ligand …

Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …

A silica‐supported precatalyst, Pd‐PEPPSI‐IPent‐SiO2, has been prepared and evaluated
for its proficiency in the Negishi cross‐coupling of hindered and electronically deactivated …

The Sonogashira cross-coupling reaction is the most frequently employed synthetic
procedure for the preparation of arylated alkynes, which are important conjugated …

The synthesis of a triethoxysilyl functionalised Pd-PEPPSI–IPr complex prepared via azide–
alkyne cycloaddition is described. The complex was immobilised onto silica gel and applied …

This review highlights the potential application and understanding of Pd (II) complexes
anchoring onto different supports as catalytic systems for the Suzuki-Miyaura reaction. The …