Non-covalent interactions (NCIs) are a vital component of biological bond-forming events,
and have found important applications in multiple branches of chemistry. In recent years, the …

Oligosaccharides have myriad functions throughout biological processes,. Chemical
synthesis of these structurally complex molecules facilitates investigation of their functions …

C‐aryl glycosyl compounds offer better in vivo stability relative to O‐and N‐glycoside
analogues. C‐aryl glycosides are extensively investigated as drug candidates and applied …

We report highly β-selective bis-thioureas-catalyzed 1, 2-cis-O-pyranosylations employing
easily accessible acetonide-protected donors. A wide variety of alcohol nucleophiles …

We report a new method for stereoselective O-furanosylation reactions promoted by a
precisely tailored bis-thiourea hydrogen-bond-donor catalyst. Furanosyl donors outfitted with …

The development of small-molecule catalysts that can effectively activate both reacting
partners simultaneously represents a pivotal pursuit in advancing the field of stereoselective …

Activation of O-glycosyl trihaloacetimidate glycosyl donors with AuCl3 as a catalyst and
pivalonitrile (t BuCN) as a ligand led to excellent glycosidation results in terms of yield and …

We report here a new catalytic method for exclusively 1, 2-cis-α-selective glycosylation that
assembles a wide variety of 1, 2-cis-aminoglycosidic linkages in complex glycans and …

Stereo-and regioselective glycosidation is still a great challenge in carbohydrate chemistry.
Among the tremendous endeavors in this area, acid–base catalysis, available to O-glycosyl …

We disclose a catalytic method for the enantio-and diastereoselective union of alkyl ethers
and heterodienes. We demonstrate that a chiral Cu–BOX complex catalyzes the efficient …