Distortion pathways of transition metal coordination polyhedra induced by chelating topology

S Alvarez - Chemical Reviews, 2015 - ACS Publications
A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

Spin state behavior of iron (II)/dipyrazolylpyridine complexes. New insights from crystallographic and solution measurements

LJK Cook, R Mohammed, G Sherborne… - Coordination Chemistry …, 2015 - Elsevier
Abstract The isomeric complexes [Fe (1-bpp) 2] 2+ and [Fe (3-bpp) 2] 2+(1-bpp= 2, 6-di
[pyrazol-1-yl] pyridine; 3-bpp= 2, 6-di [1H-pyrazol-3-yl] pyridine) and their derivatives are …

OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes

R Ketkaew, Y Tantirungrotechai, P Harding… - Dalton …, 2021 - pubs.rsc.org
OctaDist is an interactive and visual program for determination of structural distortion in
octahedral coordination complexes such as spin crossover complexes, single-ion magnets …

The rich stereochemistry of eight‐vertex polyhedra: a continuous shape measures study

D Casanova, M Llunell, P Alemany… - Chemistry–A European …, 2005 - Wiley Online Library
A stereochemical study of polyhedral eight‐vertex structures is presented, based on
continuous shape measures (CShM). Reference polyhedra, shape maps, and minimal …

Zero-field slow magnetic relaxation from single Co (II) ion: a transition metal single-molecule magnet with high anisotropy barrier

YY Zhu, C Cui, YQ Zhang, JH Jia, X Guo, C Gao… - Chemical …, 2013 - pubs.rsc.org
An air-stable star-shaped CoIICoIII3 complex with only one paramagnetic Co (II) ion in the
D3 coordination environment has been synthesized from a chiral Schiff base ligand …

Hydroxide-bridged five-coordinate Dy III single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers

J **ong, HY Ding, YS Meng, C Gao, XJ Zhang… - Chemical …, 2017 - pubs.rsc.org
A hydroxide-bridged centrosymmetric DyIII dimer with each DyIII being five-coordinated has
been synthesized using bulky hindered phenolate ligands. Magnetic studies revealed that …

Polyhedral structures with an odd number of vertices: nine‐coordinate metal compounds

A Ruiz‐Martínez, D Casanova… - Chemistry–A European …, 2008 - Wiley Online Library
The stereochemistry of nine‐coordinate transition‐metal and rare‐earth compounds has
been studied by means of continuous shape measures (CShM) and related tools. Several …

Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework

Y **n, J Wang, M Zychowicz… - Journal of the …, 2019 - ACS Publications
Microporous magnets compose a class of multifunctional molecule-based materials where
desolvation-driven structural transformation leads to the switching of magnetic properties …

Mechanistic Origin of Superionic Lithium Diffusion in Anion-Disordered Li6PS5X Argyrodites

BJ Morgan - Chemistry of Materials, 2021 - ACS Publications
The rational development of fast-ion-conducting solid electrolytes for all-solid-state lithium-
ion batteries requires understanding the key structural and chemical principles that give …

A Local D4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K**

XL Ding, YQ Zhai, T Han, WP Chen… - … A European Journal, 2021 - Wiley Online Library
Three six‐coordinate DyIII single‐molecule magnets (SMMs)[Dy (OtBu) 2 (L) 4]+ with local
D4h symmetry are obtained by optimizing the equatorial ligands. One of the compounds with …