Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites
C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …
applications of these materials in heterogeneous catalysis, mainly in the fields of …
Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis
Subnanometric metal species (single atoms and clusters) have been demonstrated to be
unique compared with their nanoparticulate counterparts. However, the poor stabilization of …
unique compared with their nanoparticulate counterparts. However, the poor stabilization of …
Aromatics production via methanol-mediated transformation routes
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
Distribution of Aluminum Species in Zeolite Catalysts: 27Al NMR of Framework, Partially-Coordinated Framework, and Non-Framework Moieties
K Chen, Z Gan, S Horstmeier… - Journal of the American …, 2021 - ACS Publications
The structure of aluminum-containing moieties in and within zeolite H-ZSM-5 catalysts is a
complex function of the elemental composition of the catalyst, synthesis conditions …
complex function of the elemental composition of the catalyst, synthesis conditions …
Role of the ionic environment in enhancing the activity of reacting molecules in zeolite pores
Tailoring the molecular environment around catalytically active sites allows for the
enhancement of catalytic reactivity through a hitherto unexplored pathway. In zeolites, the …
enhancement of catalytic reactivity through a hitherto unexplored pathway. In zeolites, the …
Selectivity descriptors for the direct hydrogenation of CO2 to hydrocarbons during zeolite-mediated bifunctional catalysis
Cascade processes are gaining momentum in heterogeneous catalysis. The combination of
several catalytic solids within one reactor has shown great promise for the one-step …
several catalytic solids within one reactor has shown great promise for the one-step …
Solvation and mobilization of copper active sites in zeolites by ammonia: consequences for the catalytic reduction of nitrogen oxides
Conspectus Copper-exchanged chabazite (Cu-CHA) zeolites are catalysts used in diesel
emissions control for the abatement of nitrogen oxides (NO x) via selective catalytic …
emissions control for the abatement of nitrogen oxides (NO x) via selective catalytic …
Selective introduction of acid sites in different confined positions in ZSM-5 and its catalytic implications
C Li, A Vidal-Moya, PJ Miguel, J Dedecek… - ACS …, 2018 - ACS Publications
Controlling the location of acid sites in zeolites can have a great effect on catalysis. In this
work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by …
work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by …
Cooperative and competitive occlusion of organic and inorganic structure-directing agents within chabazite zeolites influences their aluminum arrangement
We combine experiment and theory to investigate the cooperation or competition between
organic and inorganic structure-directing agents (SDAs) for occupancy within microporous …
organic and inorganic structure-directing agents (SDAs) for occupancy within microporous …