Insights into chemically fueled supramolecular polymers

A Sharko, D Livitz, S De Piccoli, KJM Bishop… - Chemical …, 2022 - ACS Publications
Supramolecular polymerization can be controlled in space and time by chemical fuels. A
nonassembled monomer is activated by the fuel and subsequently self-assembles into a …

Out‐of‐equilibrium supramolecular self‐assembling systems driven by chemical fuel

Q Wang, Z Qi, M Chen, DH Qu - Aggregate, 2021 - Wiley Online Library
A rich variety of smart materials developed via supramolecular assembly strategies have
been introduced in the past decades. However, most materials reside in the thermodynamic …

Tweaking a BODIPY Spherical Self‐Assembly to 2D Supramolecular Polymers Facilitates Excited‐State Cascade Energy Transfer

G Das, S Cherumukkil, A Padmakumar… - Angewandte Chemie …, 2021 - Wiley Online Library
Excited state properties such as emission, exciton transport, electron transfer, etc., are
strongly dependent on the shape, size and molecular arrangement of chromophore based …

Design and control of perylene supramolecular polymers through imide substitutions

RS Wilson‐Kovacs, X Fang… - … A European Journal, 2022 - Wiley Online Library
The number and type of new supramolecular polymer (SMP) systems have increased
rapidly in recent years. Some of the key challenges faced for these novel systems include …

Tuning the kinetic trap** in chemically fueled self‐assembly

BAK Kriebisch, CME Kriebisch… - …, 2023 - Wiley Online Library
Nature uses dynamic, molecular self‐assembly to create cellular architectures that adapt to
their environment. For example, a guanosine triphosphate (GTP)‐driven reaction cycle …

Chemical Tools for the Temporal Control of Water Solution pH and Applications in Dissipative Systems

D Del Giudice, F Frateloreto, C Sappino… - European Journal of …, 2022 - Wiley Online Library
The chemical reagents used to achieve a predictable and programmable time control of the
pH of water solutions are reviewed with the purpose to present a toolbox of instruments to be …

Functional Rhythmic Chemical Systems Governed by pH‐Driven Kinetic Feedback

B Dúzs, I Lagzi, I Szalai - ChemSystemsChem, 2023 - Wiley Online Library
Hydrogen ion autocatalytic reactions, especially in combination with an appropriate negative
feedback process, show a wide range of dynamical phenomena, like clock behavior …

Concepts and principles of self-n-do** in perylene diimide chromophores for applications in biochemistry, energy harvesting, energy storage, and catalysis

D Powell, L Whittaker-Brooks - Materials Horizons, 2022 - pubs.rsc.org
Self-do** is an essential method of increasing carrier concentrations in organic
electronics that eliminates the need to tailor host—dopant miscibility, a necessary step when …

Spinodal decomposition of chemically fueled polymer solutions

J Heckel, F Batti, RT Mathers, A Walther - Soft Matter, 2021 - pubs.rsc.org
Out-of-equilibrium phase transitions driven by dissipation of chemical energy are a common
mechanism for morphological organization and temporal programming in biology. Inspired …

Parasitic behavior in competing chemically fueled reaction cycles

PS Schwarz, S Laha, J Janssen, T Huss… - Chemical …, 2021 - pubs.rsc.org
Non-equilibrium, fuel-driven reaction cycles serve as model systems of the intricate reaction
networks of life. Rich and dynamic behavior is observed when reaction cycles regulate …