New strategies for the synthesis of aliphatic azides

P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

Strategies to Control Hypervalent Iodine–Primary Amine Reactions

A Bal, S Maiti, P Mal - Chemistry–An Asian Journal, 2020 - Wiley Online Library
The field of hypervalent iodine chemistry has been prevalent since 1886. Its journey from
obscurity to coming into the limelight has witnessed many effective transformations which …

Photocatalytic Visible-Light-Induced Nitrogen Insertion via Dual C(sp3)–H and C(sp2)–H Bond Functionalization: Access to Privileged Imidazole-based Scaffolds

SM Patel, EP P, M Bakthadoss, DS Sharada - Organic Letters, 2020 - ACS Publications
Here we have demonstrated a visible-light-mediated metal-free organic-dye-catalyzed
dehydrogenative N-insertion leading to highly substituted imidazoles and privileged …

Sodium Azide: An Inorganic Nitrogen Source for the Synthesis of Organic N‐Compounds

Z Tashrifi, MM Khanaposhtani, B Larijani… - …, 2021 - Wiley Online Library
Sodium azide (NaN3) is a colorless or white crystalline salt with diverse medicinal and
industrial applications. Recently, NaN3 is considered as an inexpensive and valuable …

Construction of Polyfunctionalized 2, 4-Dioxa-8-azaspiro [5.5] undec-9-enes and 2, 4, 8-Triazaspiro [5.5] undec-9-enes via a Domino [2+ 2+ 2] Cycloaddition Reaction

D Liu, J Sun, J **e, H Shi, CG Yan - The Journal of Organic …, 2021 - ACS Publications
The three-component reaction of α, β-unsaturated N-arylaldimines, dialkyl but-2-ynedioates,
and 2-arylidene Meldrum acids in DCM at room temperature gave mixtures of cis/trans-11 …

Exocyclic N-Acyliminium Ion (NAI) Cyclization: Access to Fully Substituted Oxazoles and Furocoumarins

VN Babu, A Murugan, N Katta, S Devatha… - The Journal of …, 2019 - ACS Publications
A concise, one-pot route to oxazoles and furocoumarins has been reported. The key step in
this transformation involves in situ generation of N-acyliminium ion (NAI) precursor under …

Di-and polyazides. Synthesis, chemical transformations and practical applications

BD Tsyrenova, PS Lemport, VG Nenajdenko - Uspehi himii, 2023 - journals.rcsi.science
The chemistry of organic di-and polyazides has been extensively developed in recent years.
Methods for the synthesis of 1, 1-and 1, 2-diazides are diverse and include stoichiometric …

Selective Construction of Diverse Polycyclic Spirooxindoles via a Three-Component Reaction of Cyclic Mercapto-Substituted β-Enamino Esters, Isatins, and Cyclic 1 …

QS Sun, J Sun, LN Pan, CG Yan - The Journal of Organic …, 2020 - ACS Publications
The three-component reaction of alkyl 2-(benzo [b][1, 4] thiazin-3-ylidene) acetates, isatins,
and 1, 3-indanedione (1, 3-cyclopentanedione) in ethanol in the presence of acetic acid …

Visible light-mediated photocatalytic oxidative cleavage of activated alkynes via hydroamination: a direct approach to oxamates

N Katta, M Ojha, A Murugan, S Arepally, DS Sharada - RSC advances, 2020 - pubs.rsc.org
The direct oxidative cleavage of activated alkynes via hydroamination has been described
using organic photocatalyst under visible-light irradiation at room temperature. In this …

Reactions with geminal diazides: long known, full of surprises, and new opportunities

K Bensberg, SF Kirsch - Synthesis, 2022 - thieme-connect.com
Geminal diazides are uncommon yet powerful tools in organic synthesis. The chemistry of
this class of functional compounds is characterized by quite unusual reactivities, including …