New strategies for the synthesis of aliphatic azides
P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …
pharmaceuticals. These compounds are also recognized as useful precursors for the …
Strategies to Control Hypervalent Iodine–Primary Amine Reactions
The field of hypervalent iodine chemistry has been prevalent since 1886. Its journey from
obscurity to coming into the limelight has witnessed many effective transformations which …
obscurity to coming into the limelight has witnessed many effective transformations which …
Photocatalytic Visible-Light-Induced Nitrogen Insertion via Dual C(sp3)–H and C(sp2)–H Bond Functionalization: Access to Privileged Imidazole-based Scaffolds
Here we have demonstrated a visible-light-mediated metal-free organic-dye-catalyzed
dehydrogenative N-insertion leading to highly substituted imidazoles and privileged …
dehydrogenative N-insertion leading to highly substituted imidazoles and privileged …
Sodium Azide: An Inorganic Nitrogen Source for the Synthesis of Organic N‐Compounds
Z Tashrifi, MM Khanaposhtani, B Larijani… - …, 2021 - Wiley Online Library
Sodium azide (NaN3) is a colorless or white crystalline salt with diverse medicinal and
industrial applications. Recently, NaN3 is considered as an inexpensive and valuable …
industrial applications. Recently, NaN3 is considered as an inexpensive and valuable …
Construction of Polyfunctionalized 2, 4-Dioxa-8-azaspiro [5.5] undec-9-enes and 2, 4, 8-Triazaspiro [5.5] undec-9-enes via a Domino [2+ 2+ 2] Cycloaddition Reaction
D Liu, J Sun, J **e, H Shi, CG Yan - The Journal of Organic …, 2021 - ACS Publications
The three-component reaction of α, β-unsaturated N-arylaldimines, dialkyl but-2-ynedioates,
and 2-arylidene Meldrum acids in DCM at room temperature gave mixtures of cis/trans-11 …
and 2-arylidene Meldrum acids in DCM at room temperature gave mixtures of cis/trans-11 …
Exocyclic N-Acyliminium Ion (NAI) Cyclization: Access to Fully Substituted Oxazoles and Furocoumarins
VN Babu, A Murugan, N Katta, S Devatha… - The Journal of …, 2019 - ACS Publications
A concise, one-pot route to oxazoles and furocoumarins has been reported. The key step in
this transformation involves in situ generation of N-acyliminium ion (NAI) precursor under …
this transformation involves in situ generation of N-acyliminium ion (NAI) precursor under …
Di-and polyazides. Synthesis, chemical transformations and practical applications
BD Tsyrenova, PS Lemport, VG Nenajdenko - Uspehi himii, 2023 - journals.rcsi.science
The chemistry of organic di-and polyazides has been extensively developed in recent years.
Methods for the synthesis of 1, 1-and 1, 2-diazides are diverse and include stoichiometric …
Methods for the synthesis of 1, 1-and 1, 2-diazides are diverse and include stoichiometric …
Selective Construction of Diverse Polycyclic Spirooxindoles via a Three-Component Reaction of Cyclic Mercapto-Substituted β-Enamino Esters, Isatins, and Cyclic 1 …
QS Sun, J Sun, LN Pan, CG Yan - The Journal of Organic …, 2020 - ACS Publications
The three-component reaction of alkyl 2-(benzo [b][1, 4] thiazin-3-ylidene) acetates, isatins,
and 1, 3-indanedione (1, 3-cyclopentanedione) in ethanol in the presence of acetic acid …
and 1, 3-indanedione (1, 3-cyclopentanedione) in ethanol in the presence of acetic acid …
Visible light-mediated photocatalytic oxidative cleavage of activated alkynes via hydroamination: a direct approach to oxamates
The direct oxidative cleavage of activated alkynes via hydroamination has been described
using organic photocatalyst under visible-light irradiation at room temperature. In this …
using organic photocatalyst under visible-light irradiation at room temperature. In this …
Reactions with geminal diazides: long known, full of surprises, and new opportunities
K Bensberg, SF Kirsch - Synthesis, 2022 - thieme-connect.com
Geminal diazides are uncommon yet powerful tools in organic synthesis. The chemistry of
this class of functional compounds is characterized by quite unusual reactivities, including …
this class of functional compounds is characterized by quite unusual reactivities, including …