3D electron diffraction for structure determination of small‐molecule nanocrystals: A possible breakthrough for the pharmaceutical industry

I Andrusenko, M Gemmi - Wiley Interdisciplinary Reviews …, 2022 - Wiley Online Library
Nanomedicine is among the most fascinating areas of research. Most of the newly
discovered pharmaceutical polymorphs, as well as many new synthesized or isolated …

Optical spin-state polarization in a binuclear europium complex towards molecule-based coherent light-spin interfaces

KS Kumar, D Serrano, AM Nonat, B Heinrich… - Nature …, 2021 - nature.com
The success of the emerging field of solid-state optical quantum information processing
(QIP) critically depends on the access to resonant optical materials. Rare-earth ion (REI) …

Key role of chromophore-modified vibrational modes on thermal broadening of single-molecule spectra in disordered solids

AO Savostianov, IY Eremchev, T Plakhotnik… - Physical Review B, 2024 - APS
For decades, the thermal broadening of zero-phonon lines of single organic molecules
embedded in amorphous solids was associated with their weak electron-phonon coupling to …

[HTML][HTML] High-resolution vibronic spectroscopy of a single molecule embedded in a crystal

J Zirkelbach, M Mirzaei, I Deperasińska… - The Journal of …, 2022 - pubs.aip.org
Vibrational levels of the electronic ground states in dye molecules have not been previously
explored at a high resolution in solid matrices. We present new spectroscopic …

Matrix‐induced linear Stark effect of single dibenzoterrylene molecules in 2, 3‐dibromonaphthalene crystal

A Moradi, Z Ristanović, M Orrit, I Deperasińska… - …, 2019 - Wiley Online Library
Absorption and fluorescence from single molecules can be tuned by applying an external
electric field–a phenomenon known as the Stark effect. A linear Stark effect is associated to …

3D electron diffraction structure determination of terrylene, a promising candidate for intermolecular singlet fission

CL Hall, I Andrusenko, J Potticary, S Gao… - …, 2021 - Wiley Online Library
Herein we demonstrate the prowess of the 3D electron diffraction approach by unveiling the
structure of terrylene, the third member in the series of peri‐condensed naphthalene …

O‐Phthalaldehyde: A Versatile Chemical with its Roles and Future Perspectives

A Misra, S Mondal… - Asian Journal of Organic …, 2024 - Wiley Online Library
Ortho‐Phthaldehyde (OPA) is one of the isomers of benzenedicarbaldehydes. It exhibits
distinctive chemical properties stemming from the closely attached dicarbaldehyde groups …

Selective vicinal diiodination of polycyclic aromatic hydrocarbons

T Kaehler, A John, T **, M Bolte… - European Journal of …, 2020 - Wiley Online Library
Vicinally diiodinated polycyclic aromatic hydrocarbons (I2‐PAHs) are accessible from the
corresponding diborylated B2‐PAHs through boron/iodine exchange. The B2‐PAHs have …

2, 3‐Dichloroanthracene crystal, a new rigid matrix for single molecule optical investigations

M Banasiewicz, I Deperasińska, P Gawryś… - …, 2024 - Wiley Online Library
Absorption and emission spectra of single crystals of 2, 3‐dichloroathracene (23DCA) and
23DCA dispersed in n‐nonane matrix were studied at 5 K. Singlet and triplet excitonic bands …

[HTML][HTML] Tubular supramolecular motifs derived from 18-membered dibenzoN4O2 macrocycle incorporated syn-C= N–O segments

OV Kulikov, V Khrustalev, S Vodzinsky - Results in Materials, 2022 - Elsevier
The novel 18-membered macroheterocycle, namely, 11, 22-dibromo-7, 8, 18, 19-
tetrahydrodibenzo [d, m]-[1, 10, 2, 6, 11, 15] dioxatetraazacyclooctadecine-6, 17 (5H, 16H) …