Visible and near-infrared light-induced photoclick reactions
Photoclick reactions combine the advantages offered by light-driven processes, that is, non-
invasive and high spatiotemporal control, with classical click chemistry and have found …
invasive and high spatiotemporal control, with classical click chemistry and have found …
Photochemically activated 3D printing inks: current status, challenges, and opportunities
Abstract 3D printing with light is enabled by the photochemistry underpinning it. Without fine
control over the ability to photochemically gate covalent bond formation by the light at a …
control over the ability to photochemically gate covalent bond formation by the light at a …
Light-sheet 3D microprinting via two-colour two-step absorption
V Hahn, P Rietz, F Hermann, P Müller… - Nature …, 2022 - nature.com
High-speed high-resolution 3D printing of polymers is highly desirable for many
applications, yet still technologically challenging. Today, optics-based printing is in the lead …
applications, yet still technologically challenging. Today, optics-based printing is in the lead …
Photocatalytic ATRP depolymerization: temporal control at low ppm of catalyst concentration
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Temporal Regulation of PET‐RAFT Controlled Radical Depolymerization
A photocatalytic RAFT‐controlled radical depolymerization method is introduced for
precisely conferring temporal control under visible light irradiation. By regulating the …
precisely conferring temporal control under visible light irradiation. By regulating the …
Photocatalytic upcycling and depolymerization of vinyl polymers
Photocatalytic upcycling and depolymerization of vinyl polymers have emerged as
promising strategies to combat plastic pollution and promote a circular economy. This mini …
promising strategies to combat plastic pollution and promote a circular economy. This mini …
Characterising different molecular landscapes in dynamic covalent networks
Dynamic covalent networks present a unique opportunity to exert molecular-level control on
macroscopic material properties, by linking their thermal behaviour to the thermodynamics …
macroscopic material properties, by linking their thermal behaviour to the thermodynamics …
Colorful 3D printing: A critical feasibility analysis of multi-wavelength additive manufacturing
Employing two colors of light to 3D print objects holds potential for accessing advanced
printing modes, such as the generation of multi-material objects from a single print. Thus …
printing modes, such as the generation of multi-material objects from a single print. Thus …
Photochemical action plots reveal the fundamental mismatch between absorptivity and photochemical reactivity
Over the last years, the authors' laboratory has employed monochromatic tuneable laser
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …
Wavelength‐Orthogonal Stiffening of Hydrogel Networks with Visible Light
Herein, we introduce the wavelength‐orthogonal crosslinking of hydrogel networks using
two red‐shifted chromophores, ie acrylpyerene (AP, λactivation= 410–490 nm) and …
two red‐shifted chromophores, ie acrylpyerene (AP, λactivation= 410–490 nm) and …